bromo-[2-[bromo(dimethyl)germyl]ethyl]-dimethylgermane | 120926-67-2

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: bromo-[2-[bromo(dimethyl)germyl]ethyl]-dimethylgermane
• CAS: 120926-67-2
• 化学式: C₆H₁₆Br₂Ge₂
• 分子量: 393.181
• InChiKey: FKIZRCCGRKRZSA-UHFFFAOYSA-N

物化性质

• 沸点：
  248.1±50.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.19
• 重原子数：
  10.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  在 溴 作用下， 以 苯 为溶剂， 以95%的产率得到bromo-[2-[bromo(dimethyl)germyl]ethyl]-dimethylgermane
  参考文献：
  名称：

  Synthesis and reactivity of digermylplatinum(II) complexes Me2tL2 (n=0, 1, 2)

  摘要：

  This work concerns the synthesis of [bis(dimethylgermyl)alkane]bis(triphenylphosphine)platine(II) and -(diphos)platine(II) Me2Ge(CH2)nGe(Me2)PtL2 (n = 2, L = PPh3 (1), diphos (2); n = l, L = PPh3 (3), diphos (4) and (tetramethyldigermyl)bis(triphenylphosphine)platine(II) and -(diphos)platine(II) Me2GeGe(Me2)PtL2 (L=PPh3 (5), diphos (6). 3 and 5 are obtained by cyclization of bis(dimethylgermyl)alkanes Me2(H)Ge(CH2)nGe(H)Me2 (n = 1 or 2) or 1,1,2,2-tetramethyldigermane Me2(H)GeGe(H)Me2 with (Ph3P)2PtC2H4. The polymeric structures [Me2Ge(CH)2)nGe(Me2)Pt(PPh3)2]m (n = 1 or 2) react with diphos to give the monomer complexes 2 or 4. IR and NMR examinations are reported. Various cleavage reactions with halogens and organic halides are described. Reactions of 2 with phenylacetylene and 1,2,4-triazolinediones afford new heterocycles arising- from formal addition of these unsaturated systems across the Ge-Ge bond of the tetramethyldigermetane Me2Ge(CH2)2GeMe2.

  DOI：

  10.1016/s0020-1693(00)92390-9

文献信息

• Nouveaux complexes à enchaînement GeRuGe: les bis(dimethylgermyl)alcane ruthenium tetracarbonyles. I. Synthèse et réactions de clivage
  作者：Jacques Barrau、Najib Ben Hamida、Jacques Satgé

  DOI：10.1016/0022-328x(90)85259-2

  日期：1990.9

  Bis(dimethylgermyl)alkane ruthenium tetracarbonyls Me2Ge(CH2)nGe(Me2)Ru(CO)4 (n = 1, 2) are obtained by reaction of bis(dimethylgermyl)alkanes Me2(H)Ge(CH2)nGe(H)Me2 (n = 1, 2) with Ru3(CO)12 under UV irradiation, or by heating. Various CO substitution reactions with phosphines by heating and cleavage reactions with protonic, electrophilic, nucleophilic or radical reagents are described. XO oxides

  双（二甲基锗烷基）烷烃四羰基钌Me 2 Ge（CH2）nGe（Me2）Ru（CO）4（n = 1，2）通过双（二甲基锗烷基）烷烃Me 2（H）Ge（CH 2）n反应制得Ge（H）Me 2（n = 1，2）与Ru 3（CO）12在紫外线辐射下或通过加热。描述了通过与质子，亲电，亲核或自由基试剂的加热和裂解反应，用膦进行的各种CO取代反应。X = O氧化物（X = Hg，C 5 H 5 N，C 6 H 5 N，Me 2S）被这些络合物脱氧。
• Bis(dimethylgermyl)alkane-iron tetracarbonyls: synthesis, photolysis, and reactivity
  作者：Jacques Barrau、Najib Ben Hamida、Abdelhamid Agrebi、Jacques Satge

  DOI：10.1021/om00109a001

  日期：1989.7
• Barrau, Jacques; Hamida, Najib Ben, New Journal of Chemistry, 1991, vol. 15, p. 657 - 664
  作者：Barrau, Jacques、Hamida, Najib Ben

  DOI：——

  日期：——