n-hexyl 4,6-bis(3,5-dimethylphenylamino)-1,3,5-triazine-2-carboxylate | 1185918-88-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: n-hexyl 4,6-bis(3,5-dimethylphenylamino)-1,3,5-triazine-2-carboxylate
• CAS: 1185918-88-0
• 化学式: C₂₆H₃₃N₅O₂
• 分子量: 447.58
• InChiKey: KLAYDKWOBVMEGA-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  methyl 4,6-bis(3,5-dimethylphenylamino)-1,3,5-triazine-2-carboxylate 、 正己醇 在 sodium 作用下， 反应 18.0h， 以77%的产率得到n-hexyl 4,6-bis(3,5-dimethylphenylamino)-1,3,5-triazine-2-carboxylate
  参考文献：
  名称：

  Anarchy in the solid state: structural dependence on glass-forming ability in triazine-based molecular glasses

  摘要：

  We have recently shown that molecular glasses, small molecules capable of readily forming glassy solids as opposed to crystals, can be designed by exploiting molecular association through strong and directional intermolecular interactions, as exemplified by several members of the bis(mexylantino)triazine family. Herein, 43 new bis(mexylamino)triazine derivatives were synthesized, 31 of which have been found to spontaneously form glassy phases and did not crystallize upon heating. Crown Copyright (C) 2009 Published by Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.07.026