四锡烷,1,1,1,2,2,3,3,4,4-九丁基-4-(2-乙氧基乙基)- | 139582-92-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 中文名称: 四锡烷,1,1,1,2,2,3,3,4,4-九丁基-4-(2-乙氧基乙基)-
• CAS: 139582-92-6
• 化学式: C₄₀H₉₀OSn₄
• 分子量: 1061.99
• InChiKey: PKQADFLTDQTSMW-UHFFFAOYSA-N

物化性质

• 沸点：
  697.4±57.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  15.25
• 重原子数：
  45.0
• 可旋转键数：
  34.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  四锡烷,1,1,1,2,2,3,3,4,4-九丁基-4-(2-乙氧基乙基)- 、 二异丁基氢化铝 以 正己烷 为溶剂， 以90-98的产率得到四锡烷,1,1,1,2,2,3,3,4,4-九丁基-
  参考文献：
  名称：

  A new strategy for the synthesis of homologously pure linear polystannane oligomers

  摘要：

  The reagent 6 is utilized for the stepwise synthesis of linear polystannane oligomers in which hydrostannolysis is employed as the Sn-Sn bond-forming reaction, and DIBAL-H is used to regenerate a new Sn-H functionality for extended chain growth through repetition of the two-step reaction sequence. The electronic spectra of these oligomers are influenced by chain length and the specific placement of substituents, as demonstrated by the homologous series 7, 9, and 13-15 and the phenylated di- and tristannanes 18-20.

  DOI：

  10.1021/om00040a007
• 作为产物：
  描述：

  二丁基(二甲氨基)(2-乙氧基乙基)锡烷 、 三锡烷,1,1,1,2,2,3,3-七丁基- 以 正己烷 为溶剂， 以60-65的产率得到四锡烷,1,1,1,2,2,3,3,4,4-九丁基-4-(2-乙氧基乙基)-
  参考文献：
  名称：

  A new strategy for the synthesis of homologously pure linear polystannane oligomers

  摘要：

  The reagent 6 is utilized for the stepwise synthesis of linear polystannane oligomers in which hydrostannolysis is employed as the Sn-Sn bond-forming reaction, and DIBAL-H is used to regenerate a new Sn-H functionality for extended chain growth through repetition of the two-step reaction sequence. The electronic spectra of these oligomers are influenced by chain length and the specific placement of substituents, as demonstrated by the homologous series 7, 9, and 13-15 and the phenylated di- and tristannanes 18-20.

  DOI：

  10.1021/om00040a007