buta-1,3-diene;ruthenium;tri(propan-2-yl)stibane | 182417-69-2

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: buta-1,3-diene;ruthenium;tri(propan-2-yl)stibane
• CAS: 182417-69-2
• 化学式: C₁₇H₃₃RuSb
• 分子量: 460.269
• InChiKey: DOXROJYWFUUWGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  molecular hydrogen;ruthenium dihydride;tri(propan-2-yl)stibane 、 1,3-丁二烯 以 苯 为溶剂， 以74%的产率得到buta-1,3-diene;ruthenium;tri(propan-2-yl)stibane
  参考文献：
  名称：

  The First Triisopropylstibane Ruthenium(II) and Ruthenium(0) Complexes Including the X‐ray Crystal Structure of [Ru(η ³ ‐C ₃ H ₅ ) ₂ (Sb i Pr ₃ ) ₂ ]

  摘要：

  AbstractThe hydridoruthenium(II) complexes [RuHCl(H2)(SbiPr3)3] (2) and [RuH2(H2(SbiPr3)3] (3), containing dihydrogen as ligand, were prepared from [RuCl2(C8H12)]n (1) as the starting material. Compound 3 reacts with CO by displacement of H2 to yield [RuH2(CO)(SbiPr3)3] (4) and with C2H4 to give both [RuH2(C2H4)2(SbiPr3)2] (5) and [RuH2(C2H4)(SbiPr3)3] (6), the latter as the more stable and isolable product. Treatment of 3 with propene leads to the formation of [Ru(η3‐C3H5)2] (7) while the reaction of 3 with butadiene affords the pentacoordinated ruthenium(0) compound [Ru(η4‐C4H6)2(SbiPr3)] (8). The molecular structure of the bis‐(allyl) complex 7 was determined by X‐ray crystallography.

  DOI：

  10.1002/cber.19961291008