dichlorocopper;2,2,8,8-tetrachloro-1,3,7,9-tetraza-2,8-disilacyclododecane | 662151-76-0

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: dichlorocopper;2,2,8,8-tetrachloro-1,3,7,9-tetraza-2,8-disilacyclododecane
• CAS: 662151-76-0
• 化学式: C₆H₁₆Cl₆CuN₄Si₂
• 分子量: 476.655
• InChiKey: UCGWBRXVMSPUAQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  吡啶 、 dichlorocopper;2,2,8,8-tetrachloro-1,3,7,9-tetraza-2,8-disilacyclododecane 以 乙醇 、 二甲基亚砜 为溶剂， 以49%的产率得到
  参考文献：
  名称：

  Heterobimetallic Complexes Containing Cu and Si

  摘要：

  [Bis(propanediamine)Cu]Cl-2, (1) was allowed to react with SiCl4 to yield a bimetallic complex (2). Compound (2) was then treated with pyridine to attain the maximum coordination number of silicon (3). The reaction was also followed conductometrically. Complex (3) was reacted with sodium diethyl dithiocarbamate (dtc) to yield (4). The dtc in (4) acts as a bidentate chelating agent as its IR spectrum showed the CS2 stretching frequency at 1020 cm(-1) I which is characteristic of a symmetrically bonded dithiocarbamate group. There is a common peak in the range 246 to 260 nm in the UV-Vis. spectra of (1), (2) and (3) due to L --> M charge transfer. The EPR spectra of all species showed different environments for the Cu(II) ion in the various compounds indicating stereochemical changes.

  DOI：

  10.1081/sim-120024322
• 作为产物：
  描述：

  四氯化硅 、 双(1,3-丙二胺)氯化铜(II) 以 四氯化碳 、 乙醇 为溶剂， 以63%的产率得到dichlorocopper;2,2,8,8-tetrachloro-1,3,7,9-tetraza-2,8-disilacyclododecane
  参考文献：
  名称：

  Heterobimetallic Complexes Containing Cu and Si

  摘要：

  [Bis(propanediamine)Cu]Cl-2, (1) was allowed to react with SiCl4 to yield a bimetallic complex (2). Compound (2) was then treated with pyridine to attain the maximum coordination number of silicon (3). The reaction was also followed conductometrically. Complex (3) was reacted with sodium diethyl dithiocarbamate (dtc) to yield (4). The dtc in (4) acts as a bidentate chelating agent as its IR spectrum showed the CS2 stretching frequency at 1020 cm(-1) I which is characteristic of a symmetrically bonded dithiocarbamate group. There is a common peak in the range 246 to 260 nm in the UV-Vis. spectra of (1), (2) and (3) due to L --> M charge transfer. The EPR spectra of all species showed different environments for the Cu(II) ion in the various compounds indicating stereochemical changes.

  DOI：

  10.1081/sim-120024322