| 717109-61-0

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• CAS: 717109-61-0
• 化学式: C₂₈H₇₆Ge₅Si₈
• 分子量: 1000.55
• InChiKey: XMNFAYRPTLFYKF-CZFRINIUSA-N

反应信息

• 作为产物：
  描述：

  germanium(II) chloride dioxane 、 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 以12%的产率得到
  参考文献：
  名称：

  Characterization of Ge₅R₄ (R = CH(SiMe₃)₂, C₆H₃-2,6-Mes₂):  Germanium Clusters of a New Structural Type with Singlet Biradical Character

  摘要：

  Reduction of the bulky organogermanium(II) halides Ge(Cl){CH(SiMe3)(2)} and Ge(Cl)C6H3-2,6-Mes(2) (the former in the presence of GeCl2.(dioxane)) afforded the clusters Ge5R4 (R = CH(SiMe3)(2) (1), C6H3-2,6-Mes(2) (2)), which have an unsubstituted germanium atom capping a butterfly Ge4R4 array. The bonding involves six two-center-two-electron Ge-Ge bonds and a lone pair at the unsubstituted germanium as well as nonbonded electron density at two of the substituted germaniums that indicates possible biradical character.

  DOI：

  10.1021/om049921z