[(Pt(3,5-dimethylpyrazolato)2(3,5-dimethylpyrazole)2)2] | 910663-67-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑啉类
• 英文名称: [(Pt(3,5-dimethylpyrazolato)2(3,5-dimethylpyrazole)2)2]
• 英文别名: [(Pt(Me2pz)2(Me2pzH)2)2]
• CAS: 910663-67-1
• 化学式: C₂₀H₃₀N₈Pt
• 分子量: 577.592
• InChiKey: HYRNBNUAXCKDSU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  银 、 [(Pt(3,5-dimethylpyrazolato)2(3,5-dimethylpyrazole)2)2] 以 not given 为溶剂， 生成 [Pt2Ag4(μ-Me2pz)8]
  参考文献：
  名称：

  Heteropolynuclear Complexes of 3,5-Dimethylpyrazolate [Pt₂M₄(Me₂pz)₈] (M = Ag, Cu). Highly Luminescent Character of the Triplet Excited State Based on Mixed-Metal Cores

  摘要：

  The platinum dimer and heteropolynuclear platinum complexes of 3,5-dimethylpyrazolate, [Pt2M4(mu-Me(2)pz)(8)] [M = H (1), Ag (2), Cu (3)], were synthesized and structurally characterized. They exhibit yellow, sky-blue, and orange luminescence, respectively, in the solid state. The absorption bands of 2 and 3 are mainly assigned to the combination of the metal-metal-to-ligand charge-transfer and [Pt-2 -> Pt2M4] transitions by the time-dependent density functional theory (DFT) method. DFT calculations also indicate that the emissive states of 2 and 3 are (3)[Pt-2 -> Pt2Ag4] and (3)[Cu(d) -> Pt2Cu4], respectively.

  DOI：

  10.1021/ic702310t