| 143693-63-4

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 143693-63-4
• 化学式: C₁₀H₂₄CoO₇*Cl₄Cu
• 分子量: 520.648
• InChiKey: DOXJQKPGNXXHRL-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  在 H₂O 作用下， 以 neat (no solvent) 为溶剂， 生成 copper(II) choride dihydrate 、
  参考文献：
  名称：

  Crystal structures of the heterometallic complex [Co · 15-crown-5 · (CH3CN)2][Cu2Cl6] and the product of its hydration [Co · 15-crown-5 · (H2O)2][CuCl4]

  摘要：

  Interaction of anhydrous CoCl2 and CuCl2 with 15C5 in acetonitrile gave the ionic complex [Co.15C5.(CH3CN)2][Cu2Cl6] (I) with the cobalt atom located in the inner cavity of the macrocycle. Thermal decomposition of I starts at 140-degrees-C with the dissociation of the acetonitrile to finally produce CoCl2 and CuCl. Hydration of I gave a mixture of CuCl2.2H2O and [Co.15C5.(H2O)2][CuCl4] (IV). Cobalt is also located in the inner cavity in IV and has a coordination number of 7.

  DOI：

  10.1016/s0277-5387(00)83243-x