| 146524-99-4

• CAS: 146524-99-4
• 化学式: C₁₂H₂₀Cl₃NZr
• 分子量: 375.881
• InChiKey: MIWBQZQRVFYZKA-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  氯化锆(IV) 、 2,5-di-tert-butylpyrrolyl lithium salt 以 甲苯 为溶剂， 以49%的产率得到
  参考文献：
  名称：

  XVI. (2,5-C4tBu2RHN)MCl3 (M  Ti, Zr, Hf; R  H, SiMe3)—Azacyclopentadienyl-Komplexe der Gruppe 4-Metalle

  摘要：

  The azacyclopentadienyl compounds (2,5-C4tBu2RHN)MCl3 (M = Ti, Zr, Hf; R = H, SiMe3) have been prepared as stable solids from the lithiated pyrroles and MCl4. The pi-coordination of the azacyclopentadienyl ligands, as suggested from C-13 NMR data, has been confirmed for (2,5-C4tBu2H2N)TiCl3 by an X-ray diffraction study.

  DOI：

  10.1016/0022-328x(92)80207-e