硅烷,二氯苯基丙基- | 17878-20-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: 硅烷,二氯苯基丙基-
• 英文名称: n-propylphenyldichlorosilane
• 英文别名: dichlorophenylpropylsilane；dichloro-phenyl-propyl-silane；Dichlor-phenyl-propyl-silan；Propyl-phenyl-dichlorsilan；Dichloro-phenyl-propylsilane
• CAS: 17878-20-5
• 化学式: C₉H₁₂Cl₂Si
• 分子量: 219.186
• InChiKey: HFMYVQVKEFPRJV-UHFFFAOYSA-N

物化性质

• 沸点：
  140-144 °C(Press: 44-47 Torr)
• 密度：
  1.08 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.22
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  氯化二苯基硅烷 在 三氯化铝 作用下， 以 neat (no solvent) 、 further solvent(s) 为溶剂， 生成 硅烷,二氯苯基丙基-
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 58, page 165 - 167

  摘要：

  DOI：

文献信息

• Dynamics of Positive Charge Carriers on Si Chains of Polysilanes
  作者：Shu Seki、Yoshiko Koizumi、Tomoyo Kawaguchi、Hidefumi Habara、Seiichi Tagawa

  DOI：10.1021/ja039840e

  日期：2004.3.1

  The transient absorption of radical cations of a variety of substituted polysilanes is discussed quantitatively in terms of the molar extinction coefficient and oscillator strength by nanosecond pulse radiolysis. Oxygen -saturated polysilane solutions in benzene exhibit a strong transient absorption band ascribed to the polysilane radical cation. The transient species react with N,N,N,N-tetramethyl-p-phenylenediamine (TMPD) to produce TMPD radical cations. On the basis of the molar extinction coefficient of the TMPD radical cation, the molar extinction coefficients for the radical cations of polysilanes are found to increase in the range 3.3 x 10(4) to 2.0 x 10(5) M(-1) cm(-1) with increasing polymer segment length. The stepwise increase in the total oscillator strength with an increase in the number of phenyl rings directly bonded to the Si skeleton suggests the delocalization of the positive polaron state and/or the SOMO state over the phenyl rings, indicating the importance of phenyl rings in intermolecular hole transfer processes.
• Barry et al., Journal of the American Chemical Society, 1947, vol. 69, p. 2916
  作者：Barry et al.

  DOI：——

  日期：——
• The Addition of Silicon Hydrides to Olefinic Double Bonds. Part V. The Addition to Allyl and Methallyl Chlorides
  作者：John W. Ryan、Gerald K. Menzie、John L. Speier

  DOI：10.1021/ja01499a031

  日期：1960.7
• Methyl octadecyl dichlorosilane
  申请人：DOW CHEMICAL CO

  公开号：US02510853A1

  公开（公告）日：1950-06-06
• Barra, A. J.; Pree, L. de; Gilkey, J. W., Journal of the American Chemical Society, 1947, vol. 69, p. 2916 - 2916
  作者：Barra, A. J.、Pree, L. de、Gilkey, J. W.、Hook, D. E.

  DOI：——

  日期：——