neopentyl(diethylamido)zinc | 195147-30-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: neopentyl(diethylamido)zinc
• CAS: 195147-30-9
• 化学式: C₉H₂₁NZn
• 分子量: 208.662
• InChiKey: VJNXWXFTFFMPSZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.79
• 重原子数：
  11.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  dineopentylzinc 、 二乙胺 以 甲苯 为溶剂， 以69%的产率得到neopentyl(diethylamido)zinc
  参考文献：
  名称：

  The properties of some volatile alkyl (di-alkylamido) zinc (11) and bis(di-alkylamido) zinc compounds: potential zinc precursors in MOCVD

  摘要：

  A series of compounds with the general formula Zn(NR2)(2) where R = Et, 'Pr, 'Bu; or RZnNR'(2) where R = Me, Et; R' = Et,'Pr,'Bu, SiMe3; and R = Np or 'Bu; R' = Et, 'Pr, 'Bu; have been synthesized and characterised. Vapour pressure measurements have been carried out to assess the potential suitability of such compounds as zinc precursors. Vapour pressures of alkyl(di-alkylamido)zinc(II) appear to be ca 5 Torr at 0 degrees C which makes then suitable zinc precursors for MOCVD (Molecular Organic Chemical Vapour Deposition) whereas bis(di-alkylamido)zinc(II) are viscous liquids with low volatility. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00116-2