(ethylenediammonium)(VF5(H2O)) | 1227374-95-9

• 英文名称: (ethylenediammonium)(VF5(H2O))
• CAS: 1227374-95-9
• 化学式: C₂H₁₀N₂*F₅H₂OV
• 分子量: 226.064
• InChiKey: LBFWLKIJNKTYCR-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氢氟酸 、 水 、 vanadia 、 乙二胺 以 乙醇 、 水 为溶剂， 以10%的产率得到(ethylenediammonium)(VF5(H2O))
  参考文献：
  名称：

  Solvatothermal chemistry of organically-templated vanadium fluorides and oxyfluorides

  摘要：

  The solvatothermal reactions of V2O5, the appropriate organoamine and HF in the temperature range 100-180 degrees C yielded a series of vanadium fluorides and oxyfluorides. The compounds [NH4][H3N(CH2)(2)NH3][VF6] (1) and [H3N(CH2)(2)NH3][VF5(H2O)] (2) contain mononuclear V(III) anions, while [H3N (CH2)(2)NH2(CH2)(2)NH3](2) [VF5(H2O)](2)[VOF4(H2O)] (3) exhibits both V(IV) and V(III) mononuclear anions. Both compound 4, [H3NCH2(C6H4)CH2NH3][VOF4]center dot H2O (4 center dot H2O) and compound 5, [HN(C2H4)(3)NH][V2O2F6(H2O)(2)] (5) contain binuclear anions constructed from edge-sharing V(IV) octahedra. In contrast, [H3N(CH2)(2)NH2(CH2)(2)NH3](2)[V4O4F14(H2O)(2)], (6) exhibits a tetranuclear unit of edge-and corner-sharing V(IV) octahedra. Compound 7, [H3N(CH2)(2)NH2][VF5], contains chains of corner-sharing {(VF6)-F-IV} octahedra, while [H2N(C2H4)(2)NH2](3)[V4F17O]center dot 1.5H(2)O (8 center dot 1.5H(2)O) is two-dimensional with a layer of V(III) and V(IV) octahedra in an edge-and corner-sharing arrangement. In the case of [H3N(CH2)(2)NH3][V2O6] (9), there was no fluoride incorporation, and the {V2O6}(n)(2n-) anion is a one-dimensional chain of corner-sharing V(V) tetrahedra. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.09.053