[CpFe(CO)(P(O)(OC6H4OMe-o)2-κP)(PhN(H)-(P(OC6H4OMe-o)2)-κP)] | 791070-46-7

• 英文名称: [CpFe(CO)(P(O)(OC6H4OMe-o)2-κP)(PhN(H)-(P(OC6H4OMe-o)2)-κP)]
• CAS: 791070-46-7
• 化学式: C₄₀H₃₉FeNO₁₀P₂
• 分子量: 811.545
• InChiKey: AUXLYEWQAXWYDQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cyclopentadienyl iron(II) dicarbonyl dimer 、 水 、 PhN(P(OC6H4OMe-o)2)2 以 甲苯 为溶剂， 以61%的产率得到[CpFe(CO)(P(O)(OC6H4OMe-o)2-κP)(PhN(H)-(P(OC6H4OMe-o)2)-κP)]
  参考文献：
  名称：

  Synthesis and derivatization, structures and transition metal (Mo(0), Fe(II), Pd(II) and Pt(II)) complexes of phenylaminobis(diphosphonite), PhN{P(OC6H4OMe-o)2}2

  摘要：

  The synthesis, derivatization and coordination behavior of a new aminobis(diphosphonite), PhN{P(OC6H4OMe-o)(2)}(2) (1) is described. The ligand 1 reacts with H2O2, elemental sulfur or selenium to give the corresponding dichalcogenides PhN{P(E)(OC6H4OMe-o)(2)}(2) (E = O, 2; S, 3; Se, 4) in good yield. Reactions of 1 with Mo(CO)(6), Pd(NCCH3)(2)Cl-2 and Pt(COD)Cl-2 resulted in the formation of the chelate complexes, Mo(CO)(4)[PhN{P(OC6H4OMe-o)(2)}(2)] (5) and MCl2[PhN{P(OC6H4OMe-o)(2)}(2)] (M = Pd,7; M = Pt, 8) whereas in the reaction of 1 with [CpFe(CO)(2)](2), one of the P-N bonds cleaves due to the metal assisted hydrolysis to give a mononuclear complex, [CpFe(CO){P(O)(OC6H4OMe-o)(2)}{PhN(H)(P(OC6H4OMe-o)(2))}] (6). The molecular structures of 1, 4, 5 and 6 are determined by X-ray studies. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.08.003