[Ni(2,2'-bipyridine)3][Ni(cis-1,2-dicyanoethylene-1,2-dithiolato)2] | 176735-70-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯嗪
• 英文名称: [Ni(2,2'-bipyridine)3][Ni(cis-1,2-dicyanoethylene-1,2-dithiolato)2]
• 英文别名: [Ni(2,2'-bipyridine)3][Ni(maleonitriledithiolato)2]
• CAS: 176735-70-9
• 化学式: C₈N₄NiS₄*C₃₀H₂₄N₆Ni
• 分子量: 866.32
• InChiKey: FQBRYNWWBUVHEX-GDNAALFUSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Ni(2,2'-bipyridyl)3](NO3)3 、 Na2[Ni(maleonitriledithiolate)2] 以 甲醇 、 水 为溶剂， 以80%的产率得到[Ni(2,2'-bipyridine)3][Ni(cis-1,2-dicyanoethylene-1,2-dithiolato)2]
  参考文献：
  名称：

  Preparation, Spectroscopic Characterization and Solid State Electrical Conductance of Bimetallic Salts of the Type [M(L—L)₃] [M′(MNT)₂]. Part II

  摘要：

  Complex bimetallic salts of the type [M(L-L)(3)][M(1) (MNT)(2)] [M = Ni(II), Zn(II), Cd(II), Fe(II), Co(II), Cu(II) and Ru(II); M(1) = NI(II) and Co(ll); L-L = 2,2'-bipyridyl (bipy); 1,10-phenanthroline (o-phen) or ethylenediamine ten); MNT 1,2-dicyano-1,2-ethylenedithiolate] have been prepared by the reaction of Na-2[M(1)(MNT)(2)] and [M(L-L)(3)]X(2). These salts have been characterized by elemental analyses, molar conductance, magnetic susceptibility, IR and UV-visible spectral studies. X-ray diffraction patterns indicate their non-isomorphous nature. All the complexes behave as semiconductors as their solid-state conductivities were found to increase with the increase in temperature from 305 to 393 K.

  DOI：

  10.1080/00945719608004767

文献信息

• Synthesis and Structural Characterization of Bimetallic Salt [Ni(phen)₃][Ni(mnt)₂] and [Ni(bpy)₃][Ni(mnt)₂]
  作者：Jia‐Sheng Zhang、Qin‐Yu Zhu、Ding‐Xian Jia、Jie Dai、De‐Qing Zhang

  DOI：10.1080/15533170500225417

  日期：2005.9.1

  complexes [Ni(phen)3][Ni(mnt)2] (1) and [Ni(bpy)3][Ni(mnt)2] (2) (mnt2−=maleonitriledithiolate) have been synthesized and characterized. X‐ray crystal structure analysis revealed that the compounds consisted of a coordinated nickel cation with distorted octahedral center and a planar [Ni(mnt)2]2−. Due to the different space effects of the cations, compound 1 is crystallized in Pī and 2 in P21/a space groups

  合成了两种新的离子对配合物 [Ni(phen)3][Ni(mnt)2] (1) 和 [Ni(bpy)3][Ni(mnt)2] (2) (mnt2−=maleonitriledithiolate)和特点。X射线晶体结构分析表明，该化合物由具有扭曲八面体中心的配位镍阳离子和平面[Ni(mnt)2]2-组成。由于阳离子的空间效应不同，化合物1分别以Pī和2在P21/a空间群中结晶，导致平面阴离子的不同堆积。发现阴离子和phen/bpy平面之间的C-H···N和C-H···S氢键较弱，C···C相互作用非常弱。1和2均在E 1/2=0.239 V处显示出可逆的单电子氧化还原波，这表明该化合物是[Ni(mnt)2]-自由基盐的优良前体。