decahydro-azepino[1,2-a]azepine | 4425-10-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂环庚烷
• 英文名称: decahydro-azepino[1,2-a]azepine
• 英文别名: Decahydro-azepino[1,2-a]azepin；decahydro-1H-azepino[1,2-a]azepine；1-azabicyclo[5.5.0]dodecane
• CAS: 4425-10-9
• 化学式: C₁₁H₂₁N
• 分子量: 167.294
• InChiKey: JFAYMIQXQSFLCC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  decahydro-azepino[1,2-a]azepine 在 高氯酸 、 乙醇 、 mercury(II) diacetate 、 溶剂黄146 作用下， 生成 1,2,3,4,5,7,8,9,10,11-decahydro-azepino[1,2-a]azepinylium; perchlorate
  参考文献：
  名称：

  Unsaturated Amines. VI. Introduction of α,β-Unsaturation by Means of Mercuric Acetate: Bicyclic Tertiary Amines^{1, 2}

  摘要：

  DOI：

  10.1021/jo01109a021
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 1,4-二氧六环 、 copper oxide-chromium oxide 作用下， 265.0 ℃ 、34.32 MPa 条件下， 生成 decahydro-azepino[1,2-a]azepine
  参考文献：
  名称：

  Reductive Cyclization. A General Method for the Synthesis of 1-Azabicyclo Compounds^1,2

  摘要：

  DOI：

  10.1021/ja01168a010

文献信息

• Organic electroluminescent device, and azepine compound and method for producing the same
  申请人：Ogasawara Jun

  公开号：US20070232800A1

  公开（公告）日：2007-10-04

  An organic electroluminescent device having a pair of electrodes, and at least one organic layer interposed between the pair of electrodes, with the organic layer containing at least one compound represented by formula (1): wherein L 11 , L 13 , and L 14 each independently represent an o-arylene group, an o-heteroarylene group, or a vinylene group; L 12 represents an o-arylene group, an o-heteroarylene group, a vinylene group, or an ethylene group; and L 15 represents a trivalent or higher aromatic ring or a trivalent or higher aromatic heterocyclic ring; and a compound represented by formula (2): wherein L 21 , L 22 , L 23 , L 24 , and L 25 each independently represent a group necessary for forming an aromatic ring or a group necessary for forming an aromatic heterocyclic ring; and a method for producing a compound represented by formula (2).

  一种具有一对电极和至少一个有机层的有机电致发光器件，该有机层位于电极对之间，所述有机层包含至少一种由式（1）表示的化合物：其中L11、L13和L14各自独立地表示o-芳基烃基、o-杂芳基烃基或乙烯基；L12表示o-芳基烃基、o-杂芳基烃基、乙烯基或乙烯基；L15表示三价或更高的芳香环或三价或更高的芳香杂环；以及一种由式（2）表示的化合物：其中L21、L22、L23、L24和L25各自独立地表示用于形成芳香环的基团或用于形成芳香杂环的基团；以及一种制备由式（2）表示的化合物的方法。
• Prelog et al., Justus Liebigs Annalen der Chemie, 1940, vol. 545, p. 229,244
  作者：Prelog et al.

  DOI：——

  日期：——
• ORGANIC ELECTROLUMINESCENT DEVICE, AN AZEPINE COMPOUND, AND A METHOD FOR MAKING THE SAME
  申请人：OGASAWARA Jun

  公开号：US20090001880A1

  公开（公告）日：2009-01-01

  An organic electroluminescent device having a pair of electrodes, and at least one organic layer interposed between the pair of electrodes, with the organic layer containing at least one compound represented by formula (1): wherein L 11 , L 13 , and L 14 each independently represent an o-arylene group, an o-heteroarylene group, or a vinylene group; L 12 represents an o-arylene group, an o-heteroarylene group, a vinylene group, or an ethylene group; and L 15 represents a trivalent or higher aromatic ring or a trivalent or higher aromatic heterocyclic ring; and a compound represented by formula (2): wherein L 21 , L 22 , L 23 , L 24 , and L 25 each independently represent a group necessary for forming an aromatic ring or a group necessary for forming an aromatic heterocyclic ring; and a method for producing a compound represented by formula (2).
• US7456567B2
  申请人：——

  公开号：US7456567B2

  公开（公告）日：2008-11-25