| 956483-66-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• CAS: 956483-66-2
• 化学式: C₂₃H₄₂O₅Si
• 分子量: 426.669
• InChiKey: XUVVGNCOHZBSLP-QHHVFILISA-N

反应信息

• 作为反应物：
  描述：

  在 sodium tetrahydroborate 、 cerium(III) chloride 、 甲醇 作用下， 以 四氢呋喃 为溶剂， 以56%的产率得到
  参考文献：
  名称：

  Synthesis of the A,B-ring-truncated OSW saponin analogs and their antitumor activities

  摘要：

  The A,B-ring-truncated OSW saponin analogs (1, 18a, and 18b) were synthesized. These greatly simplified trans-hydrin-dane disaccharides retained considerable inhibitory activity against the growth of HeLa and Jurkat T cells (IC50 = 0.8-21.1 mu M). (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmcl.2007.08.060
• 作为产物：
  描述：

  在 N-甲基吲哚酮 、 四丙基高钌酸铵 、 4 A molecular sieve 作用下， 以98%的产率得到
  参考文献：
  名称：

  Synthesis of the A,B-ring-truncated OSW saponin analogs and their antitumor activities

  摘要：

  The A,B-ring-truncated OSW saponin analogs (1, 18a, and 18b) were synthesized. These greatly simplified trans-hydrin-dane disaccharides retained considerable inhibitory activity against the growth of HeLa and Jurkat T cells (IC50 = 0.8-21.1 mu M). (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmcl.2007.08.060