[Ni(N-acetimidoylacetamidine)2]*CH3OH | 1370256-28-2

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: [Ni(N-acetimidoylacetamidine)2]*CH3OH
• CAS: 1370256-28-2
• 化学式: CH₄O*C₈H₁₆N₆Ni
• 分子量: 286.987
• InChiKey: XWHPXYJBRYGJIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 nickel(II) acetate tetrahydrate 、 乙腈 在 diphenylcarbazide 作用下， 以 甲醇 、 乙腈 为溶剂， 生成 [Ni(N-acetimidoylacetamidine)2]*CH3OH
  参考文献：
  名称：

  Co(II) and Ni(II) complexes incorporating N-acetimidoylacetamidine ligand: Synthesis and structures

  摘要：

  Two new square planar complexes with the formula Co(L)(2) center dot CH3OH (1) and Ni(L)(2) center dot CH3OH (2) (HL = HN{C(Me)=NH}(2) = N-acetimidoylacetamidine) have been synthesized by solvothermal reactions in methanol/acetonitrile. N-acetimidoylacetamidine ligand was derived from the self-condensation reaction of acetonitrile, and the reaction was promoted by the cooperation of M(II) (M = Co in 1 and M = Ni in 2) with diphenylcarbazide. 1 and 2 are characterized by single crystal X-ray diffraction, elemental analysis and infrared spectrum. Both complexes crystallize in the monoclinic space group P2(1)/c with a = 9.329(6) , b = 11.494(7) , c = 13.040(8) , beta = 92.945(11)A degrees, V = 1396.3(16) (3) and Z = 4 for 1, and a = 9.323(4), b = 11.512(5) , c = 13.020(6), beta = 92.819(7)A degrees, V = 1395.7(10)(3) and Z = 4 for 2.

  DOI：

  10.1134/s0036023612030059