C-(diisopropylamino)phosphanyl-N-(diisopropylamino)boranyl-nitrilimine | 135928-76-6

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: C-(diisopropylamino)phosphanyl-N-(diisopropylamino)boranyl-nitrilimine
• 英文别名: bis[di(propan-2-yl)amino]boranyl-[bis[di(propan-2-yl)amino]phosphanylmethylidyneazaniumyl]azanide
• CAS: 135928-76-6
• 化学式: C₂₅H₅₆BN₆P
• 分子量: 482.545
• InChiKey: RZPWHJKSIRHFCE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  C-(diisopropylamino)phosphanyl-N-(diisopropylamino)boranyl-nitrilimine 以 氘代苯 为溶剂， 以>99的产率得到N-[[bis[di(propan-2-yl)amino]phosphanyliminomethylideneamino]-[di(propan-2-yl)amino]boranyl]-N-propan-2-ylpropan-2-amine
  参考文献：
  名称：

  Synthesis of stable boryl-substituted diazomethane and nitrilimines

  摘要：

  Addition of bis(diisopropylamino)chloroborane to the lithium salt of (triisopropylsilyl)-, [bis(diisopropylamino)phosphino]-, and [bis(diisopropylamino)thioxophosphoranyl]diazomethane led to the corresponding stable N-borylnitrilimines 6-8 in 80, 90, and 95% yield, respectively. Addition of sulfur to C-phosphinonitrilimine 7 gave the thioxophosphoranyl analogue 8. The chloroborane reacted with the lithium salt of diazomethane, leading to a mixture of [bis(diisopropylamino)boryl]diazomethane (11) (54% yield) and bis[bis(diisopropylamino)boryl]nitrilimine (9) (20% yield). Compound 9 can be obtained in good yield by reacting the lithium salt of [bis(diisopropylamino]boryl]diazomethane with chloroborane. Photolysis of nitrilimines 6-9 afforded the corresponding carbodiimides 12-15. The regioselectivity and stereoselectivity of the 2 + 3 cycloaddition reactions of 6-8 with olefins were studied.

  DOI：

  10.1021/om00055a043
• 作为产物：
  描述：

  ((C₃H₇)2N)2BN₂C^(1-)*Li⁽¹⁺⁾=((C₃H₇)2N)2BN₂CLi 、 双二异丙基氨基氯化磷 以 四氢呋喃 为溶剂， 以70%的产率得到C-(diisopropylamino)phosphanyl-N-(diisopropylamino)boranyl-nitrilimine
  参考文献：
  名称：

  Arthur, Marie-Pierre; Baceiredo, Antoine; Bertrand, Guy, Journal of the American Chemical Society, 1991, vol. 113, # 15, p. 5856 - 5857

  摘要：

  DOI：

文献信息

• ARTHUR, MARIE-PIERRE;BACEIREDO, ANTOINE;BERTRAND, GUY, J. AMER. CHEM. SOC., 113,(1991) N5, C. 5856-5857
  作者：ARTHUR, MARIE-PIERRE、BACEIREDO, ANTOINE、BERTRAND, GUY

  DOI：——

  日期：——