1-(3,4-bis(2-(vinyloxy)ethoxy)phenyl)-2-(4-nitrophenyl)diazene | 1367652-41-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 1-(3,4-bis(2-(vinyloxy)ethoxy)phenyl)-2-(4-nitrophenyl)diazene
• CAS: 1367652-41-2
• 化学式: C₂₀H₂₁N₃O₆
• 分子量: 399.403
• InChiKey: VBEJGTBDBSWJET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.09
• 重原子数：
  29.0
• 可旋转键数：
  13.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  104.78
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  1-(3,4-bis(2-(vinyloxy)ethoxy)phenyl)-2-(4-nitrophenyl)diazene 在 盐酸 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 2-[2-(2-Hydroxyethoxy)-4-[(4-nitrophenyl)diazenyl]phenoxy]ethanol
  参考文献：
  名称：

  Synthesis and Properties of Novel Nonlinear Optical Polyester Containing Nitrophenylazocatecholic Group

  摘要：

  A new Y-type polyester (3) containing nitrophenylazocatecholic groups as NLO chromophores, which are parts of the polymer backbone was prepared. Polyester 3 is soluble in common organic solvents such as acetone and dimethylsulfoxide. It shows a thermal stability up to 280 degrees C from thermogravimetric analysis with glass-transition temperature (T-g ) obtained from differential scanning calorimetry near 86 degrees C. The second harmonic generation (SHG) coefficient (d(33) ) of poled polymer film at the 1064nm fundamental wavelength is around 4.42 x 10(-9) esu. The dipole alignment exhibits a thermal stability even at 4 degrees C higher than T-g , and no SHG decay was observed below 90 degrees C due to the partial main-chain character of polymer structure, which is acceptable for NLO device applications.

  DOI：

  10.1080/15421406.2013.808544
• 作为产物：
  描述：

  2-氯乙基乙烯基醚 、 4-(4-硝基苯偶氮)苯磷二酚 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以75%的产率得到1-(3,4-bis(2-(vinyloxy)ethoxy)phenyl)-2-(4-nitrophenyl)diazene
  参考文献：
  名称：

  Synthesis and Properties of Novel Polyurethane Containing Nitrophenylazocatecholic Group as NLO Chromophore

  摘要：

  DOI：

  10.5012/bkcs.2012.33.2.695

文献信息

• Synthesis and Properties of Novel Nonlinear Optical Polyurethane Containing Nitrophenylazocatecholic Group
  作者：Mi Young Song、Mi Sung Kim、Byeongman Jeon、Ju-Yeon Lee

  DOI：10.1080/15421406.2012.710192

  日期：2012.12.3

  A novel Y-type polyurethane 3 containing 4-(4-nitrophenylazo)catecholic groups as nonlinear optical (NLO) chromophores was prepared and characterized. Polyurethane 3 is soluble in common organic solvents such as acetone and DMF. Polymer 3 shows a thermal stability up to 270 degrees C from TGA thermogram and the T-g value obtained from DSC thermogram is around 96 degrees C. The second harmonic generation (SHG) coefficient (d(33)) of poled polymer film at 1064 nm fundamental wavelength is 4.58 x 10(-9) esu. The dipole alignment exhibits a thermal stability even at 4 degrees C higher than T-g, and there is no SHG decay below 100 degrees C due to the partial main-chain character of the polymer structure, which is acceptable for nonlinear optical device applications.