isopropyltin-dihydroxide-chloride | 125739-94-8

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: isopropyltin-dihydroxide-chloride
• CAS: 125739-94-8
• 化学式: C₃H₉ClO₂Sn
• 分子量: 231.266
• InChiKey: FWOZZBPYEHDGRL-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  0.56
• 重原子数：
  7.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.46
• 氢给体数：
  2.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  二甲基亚砜 、 sodium orthovanadate dodecahydrate 、 isopropyltin-dihydroxide-chloride 以 水 、 二甲基亚砜 为溶剂， 生成 Na2[(isopropyl-Sn)3(OV)4O10(OH)3]*5(water)*3(dimethylsulfoxide)
  参考文献：
  名称：

  Monoorganotin–polyoxometal-compounds. Part IV: Na2[(iPrSn3)(OV)4O10(OH)3]·5H2O·3DMSO, a novel branched tetravanadate(V) stabilized by a trimeric monoorganotin-oxo-hydroxo unit

  摘要：

  Via self-assembly of the molecular precursors sodium orthovanadate and isopropyltin-dihydroxide-chloride the unprecedented organic-inorganic hybrid polyoxoanion [((PrSn)-Pr-i)(3)(OV)(4)O-10(OH)(3)](2) was synthesized in dimethylsulfoxide (DMSO) and isolated as its sodium salt Na-2[((PrSn)-Pr-i)(3)(OV)(4)O-10(OH)(3)]center dot 5H(2)O center dot 3DMSO. This spherical nanosized anion is composed of two different structural subunits, a well-known trinuclear monoorganotin-polyoxo-hydroxo unit with octahedrally coordinated tin atoms and a new open-chain, branched isopolyoxo tetravanadate(V) with tetrahedrally coordinated vanadium atoms. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.07.055