[(η5-C5Me5)RuCl(μ2-tetramethyldiphosphine)]2 | 944538-22-1

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: [(η5-C5Me5)RuCl(μ2-tetramethyldiphosphine)]2
• 英文别名: dimethylphosphanyl(dimethyl)phosphane;1,2,3,4,5-pentamethylcyclopenta-1,3-diene;ruthenium(2+);dichloride
• CAS: 944538-22-1
• 化学式: C₂₈H₅₄Cl₂P₄Ru₂
• 分子量: 787.678
• InChiKey: BIMGKUYFWDZKOA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.67
• 重原子数：
  36
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [(η5-C5Me5)RuCl(μ2-tetramethyldiphosphine)]2 、 silver trifluoromethanesulfonate 以 四氢呋喃 为溶剂， 以89%的产率得到[(η5-C5Me5)Ru(μ2-Cl)(μ2-tetramethyldiphosphine)2Ru(η5-C5Me5)]OTf
  参考文献：
  名称：

  Synthesis and Reactivity of Diphosphine-Bridged Diruthenium Complexes

  摘要：

  Treatment of a chloride-bridged tetraruthenium complex with tetramethyldiphoshine and tetraphenyldiphosphine affords a different type of diphosphine-bridged diruthenium complexes, which are further transformed into the corresponding cationic complexes by treatment with silver trifluoromethanesulfonate. Some diphosphine-bridged diruthenium complexes show a catalytic activity toward the quantitative cyclotrimerization of ethyl propiolate to two regioisomeric benzene derivatives.

  DOI：

  10.1021/om070216a
• 作为产物：
  描述：

  chloro(pentamethylcyclopentadienyl)ruthenium(II) tetramer 、 1,1,2,2-四甲基-二膦 以 四氢呋喃 为溶剂， 以22%的产率得到[(η5-C5Me5)RuCl(μ2-tetramethyldiphosphine)]2
  参考文献：
  名称：

  Synthesis and Reactivity of Diphosphine-Bridged Diruthenium Complexes

  摘要：

  Treatment of a chloride-bridged tetraruthenium complex with tetramethyldiphoshine and tetraphenyldiphosphine affords a different type of diphosphine-bridged diruthenium complexes, which are further transformed into the corresponding cationic complexes by treatment with silver trifluoromethanesulfonate. Some diphosphine-bridged diruthenium complexes show a catalytic activity toward the quantitative cyclotrimerization of ethyl propiolate to two regioisomeric benzene derivatives.

  DOI：

  10.1021/om070216a