tris(tri-tert-butylsilyl)digallanyl | 192053-29-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: tris(tri-tert-butylsilyl)digallanyl
• 英文别名: tris(supersilyl)digallanyl；(tri-tert-butylsilyl)3Ga2；trisupersilyldigallanyl
• CAS: 192053-29-5
• 化学式: C₃₆H₈₁Ga₂Si₃
• 分子量: 737.742
• InChiKey: GTUDGOLAQSGISD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.88
• 重原子数：
  41.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  tris(tri-tert-butylsilyl)digallanyl 以 正庚烷 为溶剂， 以65.8%的产率得到tetrakis(supersilyl)-tetrahedro-tetragallane
  参考文献：
  名称：

  Tetrasupersilyl-tetrahedro-tetragallan (tBu3Si)4Ga4—ein Tetrahedran mit besonders kompaktem Ga4-Tetraedergerüst

  摘要：

  Reaction of R-2*GaX (R* = Supersilyl Si'Bu-3, X = Cl, Br) with R*Na leads in heptane at room temperature to the dark blue radical R-2(*.)-GaR* which transforms at 100 degrees C in heptane into (Bu3Si.)-Bu-t and dark violet R-4*Ga-4 (1). According to X-ray structure analysis. 1 contains a very compact Ga-4 tetrahedron (average Ga-Ga bond length 2.572 Angstrom). With oxygen, the thermo- and water-stable compound 1 reacts under formation of colorless R-4*Ga4O4 = [R*GaO](4), which after X-ray structure analysis contains a Ga4O4 heterocubane. By hydrolysis, tetrameric oxogallane R*GaO transforms into a tetrameric dihydrooxogallane R*Ga(OH)(2) which, according to X-ray structure analysis, forms chains of molecules [R*Ga(OH)(2)](4), held together by water molecules. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00836-5
• 作为产物：
  描述：

  tetra(supersilyl)cyclotrigallanyl 以 正庚烷 、 苯 为溶剂， 以15%的产率得到hexasupersilyloctagallane
  参考文献：
  名称：

  Octagallane (tBu3Si)6Ga8 and Its Reduction to (tBu3Si)6Ga82− − On the Existence of Isomeric Gallium Clusters

  摘要：

  DOI：

  10.1002/1099-0682(200203)2002:4<929::aid-ejic929>3.0.co;2-6

文献信息

• On the Gallanyls R*3Ga2· and R*4Ga3· As Well As Gallanides R*3Ga2− and R*4Ga3− (R* = SitBu3) − Syntheses, Characterization, Structures
  作者：Nils Wiberg、Thomas Blank、Kerstin Amelunxen、Heinrich Nöth、Jörg Knizek、Tassilo Habereder、Wolfgang Kaim、Matthias Wanner

  DOI：10.1002/1099-0682(200107)2001:7<1719::aid-ejic1719>3.0.co;2-q

  日期：2001.7
• Wiberg, Nils; Blank, Thomas; Amelunxen, Kerstin, European Journal of Inorganic Chemistry
  作者：Wiberg, Nils、Blank, Thomas、Amelunxen, Kerstin、Noeth, Heinrich、Schnoeckel, Hansgeorg、et al.

  DOI：——

  日期：——
• Tris(tri-tert-butylsilyl)digallanyl(tBu3Si)3Ga2: A New Type of Compound for a Heavy Group 13 Element
  作者：Nils Wiberg、Kerstin Amelunxen、Heinrich Nöth、Holger Schwenk、Wolfgang Kaim、Axel Klein、Thomas Scheiring

  DOI：10.1002/anie.199712131

  日期：1997.6.16

  Blue‐black trisupersilyldigallanyl, a new metastable inorganic radical, forms in the reaction of GaCl3 with tBu3SiNa in pentane at room temperature according to Equation (a). The X‐ray structure analysis reveals that it contains a planar Si2GaIIGaI and a nearly linear GaIIGaISi framework; according to the ESR spectrum the unpaired electron resides in both Ga atoms. Surprisingly, the analogous reaction of AlCl3 and tBu3SiNa (Al instead of Ga in Equation (a)) does not lead to trisupersilyldialanyl, but to red tetrasupersilyldialane (tBu3Si)2Al–Al(SitBu3)2. equation image