bis(trifluoroacetato)aquatris(dimethylsulfoxide)ruthenium(II) | 303988-66-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 英文名称: bis(trifluoroacetato)aquatris(dimethylsulfoxide)ruthenium(II)
• 英文别名: methylsulfinylmethane;ruthenium(2+);2,2,2-trifluoroacetate;hydrate
• CAS: 303988-66-1
• 化学式: C₁₀H₂₀F₆O₈RuS₃
• 分子量: 579.522
• InChiKey: CASRQSHKJLCWOZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  silver trifluoroacetate 、 tetrakis(dimethylsulfoxide)dichlororuthenium(II) 以 二氯甲烷 为溶剂， 以76%的产率得到bis(trifluoroacetato)aquatris(dimethylsulfoxide)ruthenium(II)
  参考文献：
  名称：

  Ruthenium carboxylate complexes [Ru(O2CR)2(H2O)(Me2SO)3] (R=Me, CF3)-synthesis and X-ray crystal structures.

  摘要：

  Reactions of [RuCl2(Me2SO)(4)] with silver carboxylates, [Ag(O2CR)] (R = Me, CF3) in cold dichloromethane afford the title compounds, [Ru(O2CR)(2)(H2O)(Me2SO)(3)] in good yield as pale cream crystals. X-ray crystal structure determinations have been performed on both complexes. In each case the geometry about the ruthenium centre is essentially octahedral with three S-bonded Me2SO ligands arranged in a fac configuration, two monodentate carboxylate anions and a coordinated H2O molecule. The carboxylate ligands are H-bonded to the H2O ligand via their non-coordinated oxygen atoms. The structures are compared with those previously reported for the alcohol dehydrogenation catalyst [Ru(O2CCF3)(2)(MeOH)(CO)(PPh3)(2)] and a closely related ruthenium carboxylate complex [Ru(O2CCF3)(2)(H2O)(PMe3)(3)]. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00432-0