| 475593-88-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑啉类
• CAS: 475593-88-5
• 化学式: C₇H₁₄BN
• 分子量: 123.006
• InChiKey: CLIJUANKTGIPRL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.97
• 重原子数：
  9.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  、 2,2,6,6-tetramethylpiperidinyl-lithium 以 not given 为溶剂， 生成
  参考文献：
  名称：

  The First General Method for the Synthesis of Transition-Metal π Complexes of an Electronically Diverse Family of 1,2-Azaborolyls

  摘要：

  A general method for the synthesis of new families of transition-metal-free 1,2-azaborolides'(3) has been developed, based on a readily available precursor (1). These azaborolides react with a variety of transition-metal electrophiles to produce an unprecedented array of eta(5)-azaborolyl adducts (4) (substituents bound to boron: nitrogen, oxygen, hydrogen, carbon, and phosphorus).

  DOI：

  10.1021/om020533b
• 作为产物：
  描述：

  三乙基硼氢化锂 、 1-tert-butyl-2-chloro-5H-azaborole 以 not given 为溶剂， 生成
  参考文献：
  名称：

  The First General Method for the Synthesis of Transition-Metal π Complexes of an Electronically Diverse Family of 1,2-Azaborolyls

  摘要：

  A general method for the synthesis of new families of transition-metal-free 1,2-azaborolides'(3) has been developed, based on a readily available precursor (1). These azaborolides react with a variety of transition-metal electrophiles to produce an unprecedented array of eta(5)-azaborolyl adducts (4) (substituents bound to boron: nitrogen, oxygen, hydrogen, carbon, and phosphorus).

  DOI：

  10.1021/om020533b