dimethyltin bis(thioacetate) | 1227456-10-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: dimethyltin bis(thioacetate)
• 英文别名: Me2Sn(SC(O)Me)2
• CAS: 1227456-10-1
• 化学式: C₆H₁₂O₂S₂Sn
• 分子量: 299.002
• InChiKey: NVJPQHKXELBVDA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dimethyltin bis(thioacetate) 、 sodium acetate 、 四甲基氯化铵 以 氯仿 为溶剂， 以60%的产率得到2,2,4,4,6,6-hexamethyl-1,3,5,2,4,6-trithiatristanninane
  参考文献：
  名称：

  Synthesis and characterization of a diorganotin bis(thioacetate)

  摘要：

  Dimethyltin bis(thioacetate) has been prepared by a reaction of dimethyltin dichloride. Attempts to prepare anionic complexes were not successful. The reactions have been explained on the basis of DFT calculations. The compound has been characterized by multinuclear NMR and IR spectral studies. X-ray study revealed that the molecular structure resembled the transition state of the trans-cis pathway of a skew trapezoid. Absorption and emission spectra of the compound have also been studied. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2010.02.043
• 作为产物：
  描述：

  二甲基二氯化锡 、 硫代乙酸 在 triethylamine 作用下， 以 四氢呋喃 为溶剂， 以80%的产率得到dimethyltin bis(thioacetate)
  参考文献：
  名称：

  Synthesis and characterization of a diorganotin bis(thioacetate)

  摘要：

  Dimethyltin bis(thioacetate) has been prepared by a reaction of dimethyltin dichloride. Attempts to prepare anionic complexes were not successful. The reactions have been explained on the basis of DFT calculations. The compound has been characterized by multinuclear NMR and IR spectral studies. X-ray study revealed that the molecular structure resembled the transition state of the trans-cis pathway of a skew trapezoid. Absorption and emission spectra of the compound have also been studied. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2010.02.043