1,2-bis(4,6-diamino-1,3,5-triazin-2-yl)diazene | 1033125-80-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 1,2-bis(4,6-diamino-1,3,5-triazin-2-yl)diazene
• 英文别名: 4,4’,6,6’-tetramino(azo)-1,3,5-triazine；6-[(4,6-Diamino-1,3,5-triazin-2-yl)diazenyl]-1,3,5-triazine-2,4-diamine；6-[(4,6-diamino-1,3,5-triazin-2-yl)diazenyl]-1,3,5-triazine-2,4-diamine
• CAS: 1033125-80-2
• 化学式: C₆H₈N₁₂
• 分子量: 248.21
• InChiKey: COXWTJAHOBBBCE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.9
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  206
• 氢给体数：
  4
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  1,2-bis(4,6-diamino-1,3,5-triazin-2-yl)diazene 在 一水合肼 作用下， 以 乙腈 为溶剂， 反应 48.0h， 生成 N,N'-bis(4,6-diamino-1,3,5-triazin-2-yl)hydrazine
  参考文献：
  名称：

  Azo bond hydrogenation with hydrazine, R–NHNH2, and hydrazobenzene

  摘要：

  Hydrogenation of azo bonds with hydrazine, mono-substituted hydrazine, and hydrazobenzene was studied with selected diazene compounds under oxygen-free conditions. The reactions proceed rapidly and in high yield in several solvents, utilizing all N-H protons. While the reduction process is accompanied by the evolution of nitrogen gas in the case of N(2)H(4), the intermediacy of diimide could not be confirmed by standard trapping experiments. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.03.083
• 作为产物：
  描述：

  N,N'-bis(4,6-diamino-1,3,5-triazin-2-yl)hydrazine 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 乙腈 为溶剂， 反应 4.0h， 以88%的产率得到1,2-bis(4,6-diamino-1,3,5-triazin-2-yl)diazene
  参考文献：
  名称：

  Azo bond hydrogenation with hydrazine, R–NHNH2, and hydrazobenzene

  摘要：

  Hydrogenation of azo bonds with hydrazine, mono-substituted hydrazine, and hydrazobenzene was studied with selected diazene compounds under oxygen-free conditions. The reactions proceed rapidly and in high yield in several solvents, utilizing all N-H protons. While the reduction process is accompanied by the evolution of nitrogen gas in the case of N(2)H(4), the intermediacy of diimide could not be confirmed by standard trapping experiments. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.03.083

文献信息

• Energetic Salts Based on an Oxygen-Containing Cation: 2,4-Diamino-1,3,5-triazine-6-one
  作者：Wei Liu、Qiu-Han Lin、Yu-Zhang Yang、Xue-Jiao Zhang、Yu-Chuan Li、Zhi-Hui Lin、Si-Ping Pang

  DOI：10.1002/asia.201301280

  日期：2014.2

  most of the salts exhibit excellent impact sensitivities (>40 J), friction sensitivities (>360 N), and are insensitive to electrostatics. The measured densities of these energetic salts range from 1.64 to 2.01 g cm−3. The detonation pressure values calculated for these salts range from 14.6 to 29.2 GPa, and the detonation velocities range from 6536 to 8275 m s−1; these values make the salts potential

  基于含氧阳离子2,4-二氨基-1,3,5-三嗪-6-6合成了具有高热稳定性和低冲击敏感性的高能盐家族，并通过IR和多核进行了全面表征（1 H，13 C）NMR光谱，元素分析和差示扫描量热法。通过将材料提交标准测试，可以了解它们对冲击，摩擦和静电的敏感性。2,4-二氨基-1,3,5-三嗪-6-硝酸盐，2,4-二氨基-1,3,5-三嗪-6-硫酸盐，2,4-二氨基-1,3的结构用单晶X射线衍射法测定了5-5-三嗪-6-一高氯酸盐，2,4-二氨基-1,3,5-三嗪-6-一5-硝基四唑酸酯。它们的密度是1.691、1.776、1.854和1.636 g cm -3， 分别。大多数盐会在超过180°C的温度下分解。尤其是2,4-二氨基-1,3,5-三嗪-6-一硝酸盐和2,4-二氨基-1,3,5-三嗪-6-一高氯酸盐在303.3和336.4°时分解C分别相当稳定。此外，大多数盐表现出优异的冲击敏感性（>