2-[(2,2-Dimethyl-1-trimethylsilyloxypropyl)-bis(trimethylsilyl)silyl]acetonitrile | 1297595-72-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 2-[(2,2-Dimethyl-1-trimethylsilyloxypropyl)-bis(trimethylsilyl)silyl]acetonitrile
• 英文别名: 2-[(2,2-dimethyl-1-trimethylsilyloxypropyl)-bis(trimethylsilyl)silyl]acetonitrile
• CAS: 1297595-72-2
• 化学式: C₁₆H₃₉NOSi₄
• 分子量: 373.834
• InChiKey: PHBOWGFQNXGIFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  33
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-[(2,2-Dimethyl-1-trimethylsilyloxypropyl)-bis(trimethylsilyl)silyl]acetonitrile 在 硫酸 作用下， 以 四氢呋喃 为溶剂， 以22%的产率得到
  参考文献：
  名称：

  Addition of Nitriles to Two Brook Silenes

  摘要：

  The addition of acetonitrile and propionitrile to two Brook silenes, (Me3Si)(2)Si=C(OSiMe3)R where R = 1-Ad and t-Bu, was examined. Products derived from addition of the alpha-CH of the nitrile across the silicon carbon double bond were identified. The reactivity of Brook silenes and naturally polarized silenes toward nitriles is compared.

  DOI：

  10.1021/om200182q
• 作为产物：
  描述：

  1-[1,1,1,3,3,3-六甲基-2-(三甲基硅烷基)-2-三硅烷基]-2,2-二甲基-1-丙酮 、 乙腈 反应 20.0h， 以89%的产率得到2-[(2,2-Dimethyl-1-trimethylsilyloxypropyl)-bis(trimethylsilyl)silyl]acetonitrile
  参考文献：
  名称：

  Addition of Nitriles to Two Brook Silenes

  摘要：

  The addition of acetonitrile and propionitrile to two Brook silenes, (Me3Si)(2)Si=C(OSiMe3)R where R = 1-Ad and t-Bu, was examined. Products derived from addition of the alpha-CH of the nitrile across the silicon carbon double bond were identified. The reactivity of Brook silenes and naturally polarized silenes toward nitriles is compared.

  DOI：

  10.1021/om200182q

文献信息

• Addition of Nitriles to Two Brook Silenes
  作者：Julie A. Hardwick、Kim M. Baines

  DOI：10.1021/om200182q

  日期：2011.5.23

  The addition of acetonitrile and propionitrile to two Brook silenes, (Me3Si)(2)Si=C(OSiMe3)R where R = 1-Ad and t-Bu, was examined. Products derived from addition of the alpha-CH of the nitrile across the silicon carbon double bond were identified. The reactivity of Brook silenes and naturally polarized silenes toward nitriles is compared.