4-[[4-[[3-[3,5-bis[3-[4-[(4-cyanophenyl)diazenyl]-N-methylanilino]-2-hydroxypropyl]-2,4,6-trioxo-1,3,5-triazinan-1-yl]-2-hydroxypropyl]-methylamino]phenyl]diazenyl]benzonitrile | 1203680-25-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 4-[[4-[[3-[3,5-bis[3-[4-[(4-cyanophenyl)diazenyl]-N-methylanilino]-2-hydroxypropyl]-2,4,6-trioxo-1,3,5-triazinan-1-yl]-2-hydroxypropyl]-methylamino]phenyl]diazenyl]benzonitrile
• CAS: 1203680-25-4
• 化学式: C₅₄H₅₁N₁₅O₆
• 分子量: 1006.1
• InChiKey: RSYQRWLMAOSCTN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  75
• 可旋转键数：
  21
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  277
• 氢给体数：
  3
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  1,3,5-tris(2-hydroxy-3-(methyl(phenyl)amino)propyl)-1,3,5-triazinane-2,4,6-trione 、 对氨基苯腈 在 硫酸 、 溶剂黄146 、 sodium nitrite 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 8.08h， 以87%的产率得到4-[[4-[[3-[3,5-bis[3-[4-[(4-cyanophenyl)diazenyl]-N-methylanilino]-2-hydroxypropyl]-2,4,6-trioxo-1,3,5-triazinan-1-yl]-2-hydroxypropyl]-methylamino]phenyl]diazenyl]benzonitrile
  参考文献：
  名称：

  分子偶氮玻璃膜上的光诱导自构表面图案：结构-性质关系和波长相关性

  摘要：

  本研究合成了三个系列的星形分子偶氮玻璃，并通过不同波长的激光辐照研究了在偶氮化合物膜上自结构化表面图案的形成。分子偶氮玻璃由三种核心前体（Tr-AN，Tr-35AN，Tr-H35AN）合成，它们是通过1,3,5-三缩水甘油基异氰脲酸酯和相应的苯胺衍生物之间的开环反应制备的。通过分别在4-氯苯胺，4-氨基苯甲腈和4-硝基苯胺的核心前体和重氮盐之间进行偶氮偶联反应获得星形偶氮化合物。通过两步反应方案，获得了三组结构不同的偶氮化合物。核心前体和偶氮化合物的特征在于使用1H NMR，FT-IR，UV-vis，质谱和热分析。通过用不同波长（488、532和589 nm）的法向入射激光束照射偶氮化合物膜，研究了在偶氮化合物膜上形成的自结构表面图案。结果表明，光致表面图案形成行为与偶氮化合物的结构，激发波长和光偏振条件密切相关。π–π *跃迁的吸收带位置主要由偶氮发色团上的吸电子基团决定。当激发波长为λ

  DOI：

  10.1021/la2027253

文献信息

• Self-Structured Surface Patterns on Molecular Azo Glass Films Induced by Laser Light Irradiation
  作者：Jianjun Yin、Gang Ye、Xiaogong Wang

  DOI：10.1021/la9041056

  日期：2010.5.4

  In this work, formation of photoinduced self-structured surface pattern and its correlation with chromophoric structures were studied by using a series of star-shaped azo compounds, which exist as stable molecular glass at room temperature. For the synthesis, a star-shaped precursor (Tr-AN) was prepared by a ring-open reaction between 1, 3, 5-triglycidyl isocyanurate and N-methylaniline. The star-shaped azo compounds were then synthesized through azo-coupling reactions between the precursor and diazonium salts of 4-nitroaniline, 2-methyl-4-nitroaniline, and 4-aminobenzonitrile, respectively. Through these steps, three azo compounds were obtained to bear different donor acceptor type azo chromophores at the peripheral positions. The formation of the photoinduced self-structured patterns was investigated by irradiating solid thin films of the molecular azo glass with a uniform laser beam (532 nm, 200 mW/cm(2)) at normal incidence. For comparison, formation of surface-relief-gratings (SRGs) was also investigated by exposing the thin films to an interference pattern of the laser beams (532 nm, 80 mW/cm(2)). The results show that SRGs can be inscribed on the films of all three star-shaped azo compounds, but self-structured surface patterns is only observed on film of the azo compound containing 4-cyanoazobenzene moieties (Tr-AZ-CN) under the same irradiation condition. The electron-withdrawing groups, which control the absorption band position, show a significant influence on both the self-structured pattern formation and SRG inscription rate. Under proper experimental conditions, both self-structured surface pattern and SRG can simultaneously be observed on the Tr-AZ-CN films. The observations can lead to a deeper understanding of the photoinduced effects, especially their correlation with molecular structures.
• Photoinduced Self-Structured Surface Pattern on a Molecular Azo Glass Film: Structure–Property Relationship and Wavelength Correlation
  作者：Xiaolin Wang、Jianjun Yin、Xiaogong Wang

  DOI：10.1021/la2027253

  日期：2011.10.18

  formation behavior is closely related to the structure of the azo compounds, excitation wavelength, and light polarization conditions. The absorption band position of the π–π* transition is mainly determined by the electron-withdrawing groups on the azo chromophores. When the excitation wavelength is between λmax and the band tail at the longer wavelength side, the self-structured surface patterns can be

  本研究合成了三个系列的星形分子偶氮玻璃，并通过不同波长的激光辐照研究了在偶氮化合物膜上自结构化表面图案的形成。分子偶氮玻璃由三种核心前体（Tr-AN，Tr-35AN，Tr-H35AN）合成，它们是通过1,3,5-三缩水甘油基异氰脲酸酯和相应的苯胺衍生物之间的开环反应制备的。通过分别在4-氯苯胺，4-氨基苯甲腈和4-硝基苯胺的核心前体和重氮盐之间进行偶氮偶联反应获得星形偶氮化合物。通过两步反应方案，获得了三组结构不同的偶氮化合物。核心前体和偶氮化合物的特征在于使用1H NMR，FT-IR，UV-vis，质谱和热分析。通过用不同波长（488、532和589 nm）的法向入射激光束照射偶氮化合物膜，研究了在偶氮化合物膜上形成的自结构表面图案。结果表明，光致表面图案形成行为与偶氮化合物的结构，激发波长和光偏振条件密切相关。π–π *跃迁的吸收带位置主要由偶氮发色团上的吸电子基团决定。当激发波长为λ