dimethylditritiogermane | 1060728-49-5

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: dimethylditritiogermane
• 英文别名: dimethylditritiumgermane；dimethyl(ditritio)germane
• CAS: 1060728-49-5
• 化学式: C₂H₈Ge
• 分子量: 108.66
• InChiKey: RUIGDFHKELAHJL-WTJCDBBSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.25
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  dimethylditritiogermane 以 not given 为溶剂， 生成 Me2GeT(1+)
  参考文献：
  名称：

  Gas phase reaction of nucleogenic dimethylgermylium cations with benzene

  摘要：

  Reaction of nucleogenic dimethylgermylium cations with benzene in the gas phase was studied by the radiochemical method. The formation of the products of germylation of benzene, dimethylphenylgermane, and phenylgermane is indicative of the formation of dimethylgermylium cations by the beta-decay of tritium in the molecule of dimethylditritium germane. Dimethylgermylium cations are shown to undergo a rearrangement in the course of the reaction with benzene, which is consistent with the earlier results of quantum-chemical calculations.

  DOI：

  10.1134/s1070363210090070
• 作为产物：
  描述：

  lithium tritide 、 二溴二甲基锗烷 在 aluminum tri-bromide 作用下， 以 二丁醚 为溶剂， 以19%的产率得到dimethylditritiogermane
  参考文献：
  名称：

  Synthesis of dimethylditritiogermane Me2GeT2

  摘要：

  A microsynthetic procedure for preparing tritium-labeled alkyl-substituted germanes is developed. The resulting dimethylditritiogermane can be used as a source of dimethylgermylium ions. The synthesis was performed by the reduction of dibromodimethylgermane with lithium tritide in presence of AlBr3.

  DOI：

  10.1134/s1070363207070080