(6S,7S,8S,9R)-9-Benzo[1,3]dioxol-5-yl-7,8-dimethyl-6,7,8,9-tetrahydro-naphtho[1,2-d][1,3]dioxol-6-ol | 375384-77-3

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基四氢萘木脂素
• 英文名称: (6S,7S,8S,9R)-9-Benzo[1,3]dioxol-5-yl-7,8-dimethyl-6,7,8,9-tetrahydro-naphtho[1,2-d][1,3]dioxol-6-ol
• CAS: 375384-77-3
• 化学式: C₂₀H₂₀O₅
• 分子量: 340.376
• InChiKey: UCKOOWAZZOXHLY-IAUOFFDSSA-N

反应信息

• 作为反应物：
  描述：

  甲氧基-三氟甲基苯 、 (6S,7S,8S,9R)-9-Benzo[1,3]dioxol-5-yl-7,8-dimethyl-6,7,8,9-tetrahydro-naphtho[1,2-d][1,3]dioxol-6-ol 生成 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (6S,7S,8S,9R)-9-benzo[1,3]dioxol-5-yl-7,8-dimethyl-6,7,8,9-tetrahydro-naphtho[1,2-d][1,3]dioxol-6-yl ester
  参考文献：
  名称：

  Three novel and one new lignan, chamaecypanones A, B, obtulignolide and isootobanone from the heartwood of Chamaecyparis obtusa var. formosana

  摘要：

  Three novel lignans, chamaecypanone A 1, chamaecypanone B 2, obtulignolide 4, and one new lignan, isootobanone 3, were isolated from the heartwood of Chamaecyparis obtusa var. formosana, and were elucidated on the basis of 2D NMR techniques. Compounds 1 and 2, derived from a phenyltetrahydronaphthalene-type lignan by cleavage and cyclization, are anthrone derivatives. Compound 3 is a phenyltetrahydronaphthalene-type lignan, and 4 is a 3,4-secophenyltetrahydronaphthalene-type lignan. The absolute configurations of 3 and otobanone 5 were elucidated by a modified Mosher's method. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)01272-2
• 作为产物：
  描述：

  isootobanone 在 sodium tetrahydroborate 作用下， 生成 (6S,7S,8S,9R)-9-Benzo[1,3]dioxol-5-yl-7,8-dimethyl-6,7,8,9-tetrahydro-naphtho[1,2-d][1,3]dioxol-6-ol
  参考文献：
  名称：

  Three novel and one new lignan, chamaecypanones A, B, obtulignolide and isootobanone from the heartwood of Chamaecyparis obtusa var. formosana

  摘要：

  Three novel lignans, chamaecypanone A 1, chamaecypanone B 2, obtulignolide 4, and one new lignan, isootobanone 3, were isolated from the heartwood of Chamaecyparis obtusa var. formosana, and were elucidated on the basis of 2D NMR techniques. Compounds 1 and 2, derived from a phenyltetrahydronaphthalene-type lignan by cleavage and cyclization, are anthrone derivatives. Compound 3 is a phenyltetrahydronaphthalene-type lignan, and 4 is a 3,4-secophenyltetrahydronaphthalene-type lignan. The absolute configurations of 3 and otobanone 5 were elucidated by a modified Mosher's method. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)01272-2