[(E)-7,7-dimethyloct-3-en-1,5-diynyl]-trimethylsilane | 71462-40-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: [(E)-7,7-dimethyloct-3-en-1,5-diynyl]-trimethylsilane
• CAS: 71462-40-3
• 化学式: C₁₃H₂₀Si
• 分子量: 204.387
• InChiKey: VKVXCSFLHNRQTF-BQYQJAHWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.47
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  [(E)-7,7-dimethyloct-3-en-1,5-diynyl]-trimethylsilane 在 sodium hydride 作用下， 以 甲醇 为溶剂， 生成 ((3E,7E,11E)-15,15-Dimethyl-hexadeca-3,7,11-triene-1,5,9,13-tetraynyl)-trimethyl-silane
  参考文献：
  名称：

  Synthesis of oligoenynes and oligomeric conjugated diacetylenes

  摘要：

  Novel oligoenynes and oligomeric conjugated diacetylenes have been synthesized via a new Pd/Cu-catalyzed reaction scheme. This Sonogashira-style preparation of oligoenynes has complementary properties to previously published procedures via ionic intermediates. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)02777-6
• 作为产物：
  描述：

  3,3-二甲基-1-丁炔 、 alkaline earth salt of/the/ methylsulfuric acid 在 哌啶 、 copper(l) iodide 、 四(三苯基膦)钯 作用下， 以 四氢呋喃 为溶剂， 生成 [(E)-7,7-dimethyloct-3-en-1,5-diynyl]-trimethylsilane
  参考文献：
  名称：

  Synthesis of oligoenynes and oligomeric conjugated diacetylenes

  摘要：

  Novel oligoenynes and oligomeric conjugated diacetylenes have been synthesized via a new Pd/Cu-catalyzed reaction scheme. This Sonogashira-style preparation of oligoenynes has complementary properties to previously published procedures via ionic intermediates. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)02777-6

文献信息

• Synthesis of oligoenynes and oligomeric conjugated diacetylenes
  作者：Michael Polhuis、Cindy C.J. Hendrikx、Han Zuilhof、Ernst J.R. Sudhölter

  DOI：10.1016/s0040-4039(02)02777-6

  日期：2003.1

  Novel oligoenynes and oligomeric conjugated diacetylenes have been synthesized via a new Pd/Cu-catalyzed reaction scheme. This Sonogashira-style preparation of oligoenynes has complementary properties to previously published procedures via ionic intermediates. (C) 2003 Elsevier Science Ltd. All rights reserved.