Gold(1+);tetradecane-1-thiolate | 1054450-59-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Gold(1+);tetradecane-1-thiolate
• CAS: 1054450-59-7
• 化学式: Au*C₁₄H₂₉S
• 分子量: 426.417
• InChiKey: GCYVIRZMVSRTMU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.23
• 重原子数：
  16
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Gold(1+);tetradecane-1-thiolate 以 四氢呋喃 为溶剂， 生成 金
  参考文献：
  名称：

  Synthesis of Gold Nanoparticles from Gold(I)−Alkanethiolate Complexes with Supramolecular Structures through Electron Beam Irradiation in TEM

  摘要：

  Monodisperse gold nanoparticles were prepared via electron beam irradiation of Au(I)-SR (R = -CnH2n+1) polymers with highly ordered supramolecular structures in transmission electron microscopy. The Au(I)-SR polymers were synthesized simply by mixing LiAuCl4 and an excess amount of alkanethiol in tetrahydrofuran. The sizes of the gold nanoparticles were controlled by changing the length of the alkyl group or by adjusting the energy of the electron beam.

  DOI：

  10.1021/ja042423x
• 作为产物：
  描述：

  四氯金(III)酸锂水合物 、 正十四烷基硫醇 以 四氢呋喃 为溶剂， 生成 Gold(1+);tetradecane-1-thiolate
  参考文献：
  名称：

  Synthesis of Gold Nanoparticles from Gold(I)−Alkanethiolate Complexes with Supramolecular Structures through Electron Beam Irradiation in TEM

  摘要：

  Monodisperse gold nanoparticles were prepared via electron beam irradiation of Au(I)-SR (R = -CnH2n+1) polymers with highly ordered supramolecular structures in transmission electron microscopy. The Au(I)-SR polymers were synthesized simply by mixing LiAuCl4 and an excess amount of alkanethiol in tetrahydrofuran. The sizes of the gold nanoparticles were controlled by changing the length of the alkyl group or by adjusting the energy of the electron beam.

  DOI：

  10.1021/ja042423x

文献信息

• US9657396B2
  申请人：——

  公开号：US9657396B2

  公开（公告）日：2017-05-23