Pd(SC6H4-2-SiPh3)2(TMEDA) | 1227099-29-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Pd(SC6H4-2-SiPh3)2(TMEDA)
• CAS: 1227099-29-7
• 化学式: C₅₄H₅₄N₂PdS₂Si₂
• 分子量: 957.759
• InChiKey: WHBCCDOZTRCEBT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四甲基乙二胺 以 二氯甲烷 、 丙酮 为溶剂， 生成 Pd(SC6H4-2-SiPh3)2(TMEDA)
  参考文献：
  名称：

  Synthesis and characterization of sterically hindered thiolate Pd(II) complexes of the type [Pd(SR)2(TMEDA)]: Examination of their catalytic properties in phosphane-free Suzuki-Miyaura cross couplings

  摘要：

  The sterically hindered thiolate complexes [Pd(SR)(2)(TMEDA)] SR = SC6F5 (2), SC6F4-4-H (3), SC6H4-2-SiPh3 (4) were easily synthesized by metathetical reactions of the corresponding palladium chloro compound [Pd(Cl)(2)(TMEDA)] (1) and the lead salt of the corresponding thiol. The identity of the three species being unequivocally determined by single crystal X-ray diffraction techniques. The catalytic activity of the palladium species [Pd(SR)(2)(TMEDA)] was explored in the Suzuki-Miyaura cross coupling reactions of different p-substituted bromobenzenes. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.08.013