silver(I) tetradecane-1-thiolate | 221683-95-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: silver(I) tetradecane-1-thiolate
• CAS: 221683-95-0
• 化学式: Ag*C₁₄H₂₉S
• 分子量: 337.318
• InChiKey: YVERYLXEPQFGBF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.23
• 重原子数：
  16.0
• 可旋转键数：
  12.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  正十四烷基硫醇 、 silver nitrate 以 水 、 甲苯 为溶剂， 生成 silver(I) tetradecane-1-thiolate
  参考文献：
  名称：

  The self-assembly of a layered material: metal-alkanethiolate bilayers

  摘要：

  Layered materials composed of metal-alkanethiolate units have been synthesized and characterized. The self-assembly occurs at the interface between a metal-ion-containing aqueous phase and an alkanethiol-containing organic phase. Key features of the structure have been determined from X-ray diffraction and infrared spectroscopy measurements. The highly ordered bilayers are characterized by tilted, all-trans alkyl chains. A new model for the inplane structure has been presented, which is based on a hexagonal arrangement of metal atoms in the central plane.

  DOI：

  10.1139/cjc-76-11-1654