triphenylmethylthiolatocopper(I) | 102840-69-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: triphenylmethylthiolatocopper(I)
• 英文别名: [Cu(triphenylmethylmercaptan(-1H))]
• CAS: 102840-69-7
• 化学式: C₁₉H₁₅S*Cu
• 分子量: 338.94
• InChiKey: RTBFQBOYOWLYON-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.52
• 重原子数：
  21.0
• 可旋转键数：
  3.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  [Cu(2-methylthio-N-(2-pyridylmethyl)acetamide(-1H))(triphenylmethylmercaptan(-1H))] 以 四氢呋喃 为溶剂， 生成 [Cu(2-methylthio-N-(2-pyridylmethyl)acetamide(-1H))Cl(MeOH)] 、 triphenylmethylthiolatocopper(I)
  参考文献：
  名称：

  Synthesis, Characterization, and Reactivity of New Copper(II) Complexes of 2-Methylthio-N-(2-pyridylmethyl)acetamide

  摘要：

  Copper(II) complexes were prepared with the new N2S(thioether) ligand 2-methylthio-N-(2-pyridylmethyl)acetamide (2-HLN2S). [Cu(2-L-N2S)Cl(MeOH)], which formed in the presence of excess triethylamine, is a distorted square pyramidal complex containing the ligand with the amide nitrogen deprotonated. The structurally analogous complex, [Cu(2-HLN2S)Cl-2], which formed in the absence of triethylamine, contains 2-HLN2S in the tautomeric imidic acid form. Neutral copper(II) N2S(thioether)S(thiolate) species were generated by addition of alkyl or aromatic thiolates to [Cu(2-L-N2S)Cl(MeOH)] and an unusual decomposition pathway was discovered.

  DOI：

  10.1021/ic049136e

文献信息

• The preparation and crystal structure of the unusual copper–sulphur cage complex Cu₈(SC₅H₁₁)₄(S₂CSC₅H₁₁)₄
  作者：R. Chadha、Rajesh Kumar、Dennis G. Tuck

  DOI：10.1039/c39860000188

  日期：——

  The electrochemical oxidation of anodic copper in an acetonitrile solution of RSH (R = Ph, C10H7, CPh3, C6F4H, o-MeC6H4, CMe2Et) yields CuSR; treatment of CuSCMe2Et with CS2 produces Cu8(SR)4(S2CSR)4, whose structure is based on an unusual Cu8S12 cage.

  阳极铜在 RSH（R = Ph、C10H7、CPh3、C6F4H、o-MeC6H4、CMe2Et）的乙腈溶液中发生电化学氧化反应，生成 CuSR；CuSCMe2Et 与 CS2 处理后生成 Cu8(SR)4(S2CSR)4，其结构基于一个不寻常的 Cu8S12 笼。
• Chadha, Raj K.; Kumar, Rajesh; Tuck, Dennis G., Canadian Journal of Chemistry, 1987, vol. 65, p. 1336 - 1342
  作者：Chadha, Raj K.、Kumar, Rajesh、Tuck, Dennis G.

  DOI：——

  日期：——