| 343570-15-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 343570-15-0
• 化学式: C₁₂H₂₉Cl₃N₃PTi
• 分子量: 400.595
• InChiKey: LAWUVYCADZGKDF-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  四氯化钛 、 aminobis(diisopropylamino)phosphane 在 (C₂H₅)3N 作用下， 以 四氢呋喃 为溶剂， 以61%的产率得到
  参考文献：
  名称：

  (NH)-Phosphanylamido- and (PH)-Phosphoraneiminato Transition-Metal Complexes:  Syntheses, Structures, and Computational Studies

  摘要：

  Reactions of aminobis(diorganylamino)phosphanes (R2N)(2)PNH2 (R = iPr (a), Cy (b)) with Cp2MCl2 (M = Ti, Zr, Hf), CpTiCl3, and TiCl4 lead to the formation of the transition-metal complexes (R2N)(2)PN(H)MCp2Cp2Cl (M=Ti (1b), Zr (2a,b) Hf (3a,b)) (R2N)(2)P(H)NTiCpCl2 (8a,b), and (R2N)(2)P(H)NTiCl3 (10a,b), respectively. The influence of electronic effects of the metal fragment on the resulting equilibrium between the (NH)-phosphanylamido and the tautomeric (PH-iminophosphorane form is presented in detail.; Computational studies unambiguously confirm the experimental results. The molecular structures of 2a, 3a, and 8b have been determined by single-crystal S-ray diffraction.

  DOI：

  10.1021/om000967b