Piperidine, 1-[chloro(triphenylgermyl)boryl]-2,2,6,6-tetramethyl- | 351345-75-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: Piperidine, 1-[chloro(triphenylgermyl)boryl]-2,2,6,6-tetramethyl-
• 英文别名: (chloro)-(2,2,6,6,-tetramethylpiperidino)(triphenylgermyl)borane
• CAS: 351345-75-0
• 化学式: C₂₇H₃₃BClGeN
• 分子量: 490.42
• InChiKey: AAZZQUNAODUALZ-UHFFFAOYSA-N

物化性质

• 沸点：
  506.1±33.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.01
• 重原子数：
  31.0
• 可旋转键数：
  5.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  triphenylgermyllithium-diethylether(1/3) 、 Piperidine, 1-[chloro(triphenylgermyl)boryl]-2,2,6,6-tetramethyl- 生成 (2,2,6,6,-tetramethylpiperidino)bis(triphenylgermyl)borane
  参考文献：
  名称：

  氨基(三苯基锗基)硼烷和三氢(三苯基锗基)硼酸盐的合成与结构

  摘要：

  The B-(triphenylgermyl)borazines 4a and 4b, the 1,2-bis(dimethylamino) -1,2-bis(triphenylgermyl)-diborane(4), 5, and the (2,2,6,6-tetramethylpiperidino)(triphenylgermyl) boranes 6 and 7 were prepared by allowing LiGePh3 to react with the corresponding B-bromoborazines and amino-chloroboranes, respectively. BH3 dissolved in thf readily adds to LiGePh3 generating Li(H3BGePh3), 8a, in thf solution. Addition of N-bases to the solution of 8a produced (tmen thf)Li(H3BGePh3), 8b, and dimeric (py)(2)Li(H3BGePh3), Sc. The borazine ring in 4b is distorted into a boat shape. In 5 the NBGe planes are twisted against each other by 85 degrees. Comparison with analogous (triphenylstannyl)boranes points to a more pronounced steric effect of the Ph3Ge group over the Ph3Sn group due to the shorter B-Ge bond. A fairly short B-Ge bond is found for the (triphenylgermyl)trihydroberates. The molecular structure of (Et2O)(3)LiGePh3 shows compressed C-Ce-C bond angles. Its molecular parameters fit well into the series LnLiEPh3 (E = Si, Sn, Pb).

  DOI：

  10.1002/1521-3749(200105)627:5<1003::aid-zaac1003>3.0.co;2-e
• 作为产物：
  描述：

  三苯基氢化锗 以 乙醚 、 正己烷 为溶剂， 生成 Piperidine, 1-[chloro(triphenylgermyl)boryl]-2,2,6,6-tetramethyl-
  参考文献：
  名称：

  氨基(三苯基锗基)硼烷和三氢(三苯基锗基)硼酸盐的合成与结构

  摘要：

  The B-(triphenylgermyl)borazines 4a and 4b, the 1,2-bis(dimethylamino) -1,2-bis(triphenylgermyl)-diborane(4), 5, and the (2,2,6,6-tetramethylpiperidino)(triphenylgermyl) boranes 6 and 7 were prepared by allowing LiGePh3 to react with the corresponding B-bromoborazines and amino-chloroboranes, respectively. BH3 dissolved in thf readily adds to LiGePh3 generating Li(H3BGePh3), 8a, in thf solution. Addition of N-bases to the solution of 8a produced (tmen thf)Li(H3BGePh3), 8b, and dimeric (py)(2)Li(H3BGePh3), Sc. The borazine ring in 4b is distorted into a boat shape. In 5 the NBGe planes are twisted against each other by 85 degrees. Comparison with analogous (triphenylstannyl)boranes points to a more pronounced steric effect of the Ph3Ge group over the Ph3Sn group due to the shorter B-Ge bond. A fairly short B-Ge bond is found for the (triphenylgermyl)trihydroberates. The molecular structure of (Et2O)(3)LiGePh3 shows compressed C-Ce-C bond angles. Its molecular parameters fit well into the series LnLiEPh3 (E = Si, Sn, Pb).

  DOI：

  10.1002/1521-3749(200105)627:5<1003::aid-zaac1003>3.0.co;2-e