cobalt(III) dimethyldithiocarbamate*I2 | 933770-73-1

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: cobalt(III) dimethyldithiocarbamate*I2
• 英文别名: Co(Me2Dtc)3*I2
• CAS: 933770-73-1
• 化学式: C₉H₁₈CoN₃S₆*I₂
• 分子量: 673.46
• InChiKey: AMPRHQFFYGKRGX-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  2.91
• 重原子数：
  21.0
• 可旋转键数：
  0.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  9.72
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  [cobalt(III)(N,N-dimethyldithiocarbamate)3] 、 碘 以 乙醚 、 氯仿 为溶剂， 生成 cobalt(III) dimethyldithiocarbamate*I2
  参考文献：
  名称：

  Khitrich; Seifullina; Starikova, Russian Journal of Inorganic Chemistry, 2002, vol. 47, # 1, p. 80 - 86

  摘要：

  DOI：

文献信息

• Interaction between N,N,N′,N′-tetramethylthiuram disulfide and cobalt(II) salts: Dependence of the product composition and structure on the nature of the anion
  作者：N. V. Khitrich、I. I. Seifullina、S. E. Nefedov、A. V. Mazepa

  DOI：10.1134/s0036023606070059

  日期：2006.7

  The reaction between CoX2 (X = Br, I, NCS, NO3) and N,N,N',N'-tetramethylthiuram disulfide is found to be a redox process. Irrespective of the anion, it yields cobalt(III) dimethyldithiocarbamate Co(Me(2)Dtc)(3)}. The other products vary in number and composition: Me(4)Ditt[CoBr4] forms for X = Br; Me(2)Tmi[I-3], S, and Co(Me(2)Dtc)(3) center dot I-2, for X = I; [Co(Me(2)Ditc)(4)](NCS)(2), for X = NCS; CoSO4 center dot 7H(2)O and NO, for X = NO3 (Me(4)Ditt = 3,6-di(dimethyliminio)-1,2,4,5-tetrathian, Me(2)Tmi = dimethylthioxomethylideneimonium, and Me(2)Ditc = dimethyldithiocarbamatoisothiocyanate). The compounds have been characterized by chemical analysis, X-ray diffraction, mass spectrometry, conductivity measurements, IR and electronic spectroscopy, and magnetic measurements. The structure of Co(Me(2)Dtc)(3) center dot I-2 was determined by X-ray crystallography.