Diaethyl-aethoxy-gallan | 85394-11-2

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Diaethyl-aethoxy-gallan
• 英文别名: diethylethoxygallium；Ethoxy(diethyl)gallane
• CAS: 85394-11-2
• 化学式: C₆H₁₅GaO
• 分子量: 172.907
• InChiKey: UTEOMMJNQNHPJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.05
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Diaethyl-aethoxy-gallan 、 sodium hydride 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Preparation, characterization, and application of fine metal particles and metal colloids using hydrotriorganoborates

  摘要：

  The reduction of transition metal salts and oxides using hydrotriorganoborates in organic media allows the production of X-ray amorphous nanopowders of metals and alloys under mild conditions. For example, the reduction of needle-shaped iron oxides at 80-degrees-C in organic solvents leads to acicular iron-magnet pigments suitable for recording magnetic signals. The reduction of TiCl4 with K[BEtH] gives an ether-soluble [Ti(0).0.5THF]x which serves as a catalyst for the hydrogenation of titanium or zirconium sponges and related systems and as a powerful activator for heterogeneous hydrogenation catalysts. The use of tetraalkylammonium hydrotriorganoborates as reducing agents leads to colloidal transition metals in organic phases. These colloids may also be obtained using conventional reducing agents after first reacting the metal salts with the stabilizing tetraalkylammonium halide. Colloidal metals prepared in this way serve as sources for heterogeneous metal catalysts.

  DOI：

  10.1016/0304-5102(93)e0148-a
• 作为产物：
  描述：

  diethyl(ethylperoxy)gallane 、 甲苯 生成 Diaethyl-aethoxy-gallan
  参考文献：
  名称：

  ALEKSANDROV, YU. A.;CHIKINOVA, N. V.;MAKIN, G. I.;BREGADZE, V. I.;GOLUBIN+, METALLOORGAN. XIMIYA, 2,(1989) N, S. 524-529

  摘要：

  DOI：