5,10,15-tris(pentafluorophenyl)corrole cobalt(III) triphenyl phosphine | 226922-76-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 5,10,15-tris(pentafluorophenyl)corrole cobalt(III) triphenyl phosphine
• 英文别名: 5,10,15-tris-pentafluorophenylcorrolato-cobalt(III) triphenylphosphine；5,10,15-tris(pentafluorophenyl)cobalt(III) corrole；(tpfc)Co-PPh3；meso-5,10,15-tris(pentafluorophenyl)corrole Co(III)-PPh₃；(C6H5)3PCo(5,10,15-tris(pentafluorophenyl)corrole)；[Co(tpfc)PPh3]
• CAS: 226922-76-5
• 化学式: C₅₅H₂₃CoF₁₅N₄P
• 分子量: 1114.76
• InChiKey: IHBNEVGWMXVTFV-XDBICYDFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  5,10,15-tris(pentafluorophenyl)corrole cobalt(III) triphenyl phosphine 、 三乙胺 在 对三联苯 作用下， 以 乙腈 为溶剂， 生成 (C2H5)2NCHCH3Co(5,10,15-tris(pentafluorophenyl)corrole)
  参考文献：
  名称：

  Reduction of Cobalt and Iron Corroles and Catalyzed Reduction of CO₂

  摘要：

  The role of cobalt and iron corroles in catalytic CO2 reduction has been studied. Chemical, electrochemical, and photochemical reductions of the stable metal corroles Ph3PCoIII(tpfc) (tpfc = 5,10,15-tris(pentafluorophenyl)corrole), ClFeIV(tpfc), and CIFeIV(tdcc) (tdcc = 5,10,15-tris(2,6-dichlorophenyl)corrole) have been carried out in acetonitrile solutions. Stepwise reduction to the [M-II(tpfc)](-) and [M-1(tpfc)](2-) states was observed in all cases. Gradual reduction with sodium amalgam permitted recording of the optical absorption spectra of the various oxidation states and showed that the M-1 s