mono(pentakis(ethylamino)cobalt(VIII)) monobromide | 61181-52-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: mono(pentakis(ethylamino)cobalt(VIII)) monobromide
• CAS: 61181-52-0
• 化学式: C₁₀H₃₅BrCoN₅
• 分子量: 364.319
• InChiKey: DAXNJUMCUIVKTK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 氢溴酸 以 not given 为溶剂， 生成 mono(pentakis(ethylamino)cobalt(VIII)) monobromide
  参考文献：
  名称：

  Kinetic studies on sterically hindered pentaaminecobalt(III) complexes. Synthesis, anation reactions and crystal structure of [Co(EtNH2)5H2O] (ClO4)3·2H2O

  摘要：

  The sterically hindered pentakis(ethylamine)aquacobalt(III) complex has been prepared and its perchlorate dihydrate salt characterized by X-ray spectroscopy. Anation reactions of this complex with Cl-, Br-, CF3COO-, H2PO4- and H3PO4 have been studied as a function of temperature, and the results compared with those previously obtained for other [Co(RNH2)5H2O]3+ (R = H, Me) systems. Comparison of the bond distances of the title compound with those of the corresponding pentaammine complex leads to the conclusion that the increasing steric demands of the am(m)ine ligands are responsible for the clear rate acceleration observed in the dissociative activation anation process.

  DOI：

  10.1016/s0020-1693(00)81662-x