| 45657-46-3

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 45657-46-3
• 化学式: C₄H₆N₂S₂*Ni
• 分子量: 204.927
• InChiKey: KGSIVAQHMBRNLE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.65
• 重原子数：
  9.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  28.2
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  nickel(II) nitrate hexahydrate 、 N,N'-二甲基二硫代乙酰胺 在 Na-acetate 作用下， 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Nickel(II) Complexes of N,N'-Disubstituted Dithiooxamides¹

  摘要：

  N,'N'-Dimethyl- (I), N-,N'-dibenzyl- (II), N,N-'-dioctadecyl- (III), N,N'-bis-(2-hydroxyethy1)- (IV), N,N'-bis-(2-acetoxyethyl)- (V) and N,N'-bis-(3-dimethylaminopropyl)-dithiooxamide (VI) formed intensely colored nickel complexes (VII-XII), respectively. N,N'-Dimethyldithiooxamidonickel(II) (VII) is a low polymer whose size and terminal structure are dependent on both the manner of preparation and purification. VII is crystalline and paramagnetic. N,N'-Bis-(2-hydroxy-ethyl)-dithiooxamidonickel(II) (X) was acetylated, but the product (XIV) contains only half the number of acetyl groups of N,N'-bis-(2-acetoxyethyl)-dithiooxamidonickel (II) (XI) prepared directly from V. The reaction of I with trisethyleuediaminenickel(II) ion gave a complex product (XIII) differing from VII. Certain primary alkylamines were found to react with I, and in the case of trisethvlenediaminenickel(II) ion, such reaction may have occurred during the formation of XIII.

  DOI：

  10.1021/ja01502a004

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.C2, 8.15, page 998 - 1009
  作者：

  DOI：——

  日期：——