| 219991-37-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• CAS: 219991-37-4
• 化学式: C₃₆H₄₀N₄Na₂NiO₁₀S₄
• 分子量: 921.668
• InChiKey: QWYNOUPGZNKKRD-WIVWRBNZSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 苯并-15-冠醚-5 、 disodium maleonitriledithiolato 以 甲醇 、 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  One-dimensional co-ordination polymers formed by crown ether metal cation bridges: synthesis and crystal structure of nickel(II) dithiolene complexes [{Na(benzo-15-crown-5)}2 Ni(i-mnt)2]n · nCH2Cl2 and [{Na(benzo-15-crown-5)}2Ni(mnt)2]n

  摘要：

  Reaction of NiCl2. 6H(2)O, Na-2[i-mnt] and benzo-15-crown-5 in CH3OH/CH2Cl2 at room temperature leads to [{Na(benzo-15-crown-5)}(2)Ni(mnt)(2)](n) . nCH(2)Cl(2) (1). The same reaction with Na-2[mnt] instead of Na-2[i-mnt] affords [{Na(benzo-15-crown-5)}(2)Ni(mnt)(2)](n) (2). Both complexes were isolated as crystalline products. X-ray diffraction analyses reveal that the main segments of 1 and 2 are infinite "train" structures, in which the building blocks Ni(i-mnt), or Ni(mnt), in end-to-end arrangements act as "body frames" and crown cycles standing by the body frames play the role of "cartwheel". They are joined with each other through sodium ions. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00195-8