2,2,3,3,4,4-hexafluoro-1,5-bis(5,5-dimethyl-1,3,2-dioxaphosphorinan-2-yloxy)pentane | 381732-46-3

• 分子结构分类: 有机化合物 - 有机磷化合物 - 亚磷酸三烷基酯
• 英文名称: 2,2,3,3,4,4-hexafluoro-1,5-bis(5,5-dimethyl-1,3,2-dioxaphosphorinan-2-yloxy)pentane
• 英文别名: 2-[5-[(5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy]-2,2,3,3,4,4-hexafluoropentoxy]-5,5-dimethyl-1,3,2-dioxaphosphinane
• CAS: 381732-46-3
• 化学式: C₁₅H₂₄F₆O₆P₂
• 分子量: 476.29
• InChiKey: XZISDAJLSQDFPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  29
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  55.4
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  2,2,3,3,4,4-hexafluoro-1,5-bis(5,5-dimethyl-1,3,2-dioxaphosphorinan-2-yloxy)pentane 在 sulfur 作用下， 以 1,4-二氧六环 为溶剂， 反应 6.0h， 以47%的产率得到2,2,3,3,4,4-hexafluoro-1,5-bis(5,5-dimethyl-2-thioxo-1,3,2λ⁵-dioxaphosphorinan-2-yloxy)pentane
  参考文献：
  名称：

  摘要：

  2-Polyfluoroalkoxy-1,3,2-dioxaphosphorinanes and related phosphocyclic compounds were prepared by alcoholysis of 2-amino-1,3,2-dioxaphosphorinanes with polyfluorinated alcohols. Principal chemical properties of the products were studied. For the first time copper complexes of fluorine-containing normal phosphites were prepared. A difference in the ligation of copper with fluorinated and nonfluorinated phosphites was shown.

  DOI：

  10.1023/a:1012362630312
• 作为产物：
  描述：

  2,2,3,3,4,4-六氟环-1,5-戊二醇 、 2-diethylamino-5,5-dimethyl-1,3,2-dioxaphosphorinane 生成 2,2,3,3,4,4-hexafluoro-1,5-bis(5,5-dimethyl-1,3,2-dioxaphosphorinan-2-yloxy)pentane
  参考文献：
  名称：

  摘要：

  2-Polyfluoroalkoxy-1,3,2-dioxaphosphorinanes and related phosphocyclic compounds were prepared by alcoholysis of 2-amino-1,3,2-dioxaphosphorinanes with polyfluorinated alcohols. Principal chemical properties of the products were studied. For the first time copper complexes of fluorine-containing normal phosphites were prepared. A difference in the ligation of copper with fluorinated and nonfluorinated phosphites was shown.

  DOI：

  10.1023/a:1012362630312