{Ni(SeCN)2en2} | 15555-48-3

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: {Ni(SeCN)2en2}
• 英文别名: ethane-1,2-diamine;nickel(2+);diisoselenocyanate
• CAS: 15555-48-3
• 化学式: C₆H₁₆N₆NiSe₂
• 分子量: 388.843
• InChiKey: AOGRJDDQDWCMER-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II)(ethylenediamine)2Cl2 、 potassium selenocyanate 以 水 为溶剂， 生成 {Ni(SeCN)2en2}
  参考文献：
  名称：

  Spacu, G.; Macarovici, C. G., Buletinul Societatii de Stiinte din Cluj, 1930, vol. 5, p. 169 - 187

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.C1, 69, page 166 - 168
  作者：

  DOI：——

  日期：——
• Mononuclear bis-chelate and tris-chelate complexes of nickel(II) with selenocyanate. Molecular structure of [Ni(en)3]cis-[Ni(en)2(NCSe)2]2X2 (X  PF6−, ClO4− and SeCN−) and trans-[Ni(en)2(NCSe)2]
  作者：Joan Ribas、Montserrat Monfort、Inmaculada Resino、Barindra Kumar Ghosh、Xavier Solans、Mercé Font-Bardia

  DOI：10.1016/s0277-5387(97)00444-0

  日期：1998.1

  The reaction of Ni(ClO4)(2).aq, ethylenediamine (en) and KSeCN afford mononuclear [Ni(en)(3)][Ni(en)(2)(NCSe)(2)](2)(ClO4)(SeCN) (1) complexes. The same reaction starting with Ni(NO3)(2).aq with or without KPF6 affords two different compounds: [Ni(en)(3)][Ni(en)(2)(NCSe)(2)](2)(PF6)(2) (2) and [Ni(en)(2)(NCSe)(2)] (3). The structures of the three compounds were determined by X-ray crystallography. The structures of compounds (1) and (2) were very similar, consisting of two discrete mononuclear Ni(II) complexes, one tris-chelate and the other cis bis-chelate with the two selenocyanato ligands linked by the nitrogen atoms. The structure of complex (3) is different and consisted of a discrete neutral mononuclear Ni(II) complex trans bis-chelate with the two selenocyanato ligands also linked by the nitrogen atoms. Structures, synthetic trends and magnetic behaviour are discussed. (C) 1998 Elsevier Science Ltd. All rights reserved.