(1-ethyl-pentyloxy)-trimethyl-silane | 18132-91-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: (1-ethyl-pentyloxy)-trimethyl-silane
• 英文别名: (1-Aethyl-pentyloxy)-trimethyl-silan；3-Heptanol-trimethylsilylether；3-Trimethylsilyloxyheptane；heptan-3-yloxy(trimethyl)silane
• CAS: 18132-91-7
• 化学式: C₁₀H₂₄OSi
• 分子量: 188.385
• InChiKey: BFXQFCFTGYRBAE-UHFFFAOYSA-N

物化性质

• 沸点：
  188.3±8.0 °C(Predicted)
• 密度：
  0.7908 g/cm3(Temp: 25 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  3.81
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (1-ethyl-pentyloxy)-trimethyl-silane 在 1-benzyl-1-azonia-4-azabicyclo[2.2.2]octane tetrahydroborate 作用下， 以 叔丁醇 为溶剂， 反应 4.0h， 以100%的产率得到3-庚醇
  参考文献：
  名称：

  Facile Deprotection of Trimethylsilyl Ethers With Modified Borohydride Agents; 1-Benzyl-4-AZA-1-Azoniabicyclo[2.2.2]Octane Tetrahydroborate (Baaotb)¹Versus Tetrabutylammonium Tetrahydroborate(TBATB)

  摘要：

  Deprotection of structurally different trimethylsilyl ethers with the modified borohydride agents BAAOTB and TBATB to their corresponding alcohols in reflexing t-BuOH is described. Both BAAOTB and TBATB are efficient reagents for this purpose. BAAOTB seems to be more selective than TBATB.

  DOI：

  10.1080/00397919608003713
• 作为产物：
  描述：

  3-庚醇 、 六甲基二硅氮烷 生成 (1-ethyl-pentyloxy)-trimethyl-silane
  参考文献：
  名称：

  Consensus Among Economists: Revisited

  摘要：

  The authors explore consensus among economists on specific propositions on the basis of a fall 2000 survey of American Economic Association members. Because some propositions are drawn from earlier studies, the results illustrate the dynamics of opinion within the profession. The authors generally find consensus within the profession, although the degree of consensus varies between propositions that are international, macroeconomic, and microeconomic in nature. Consensus is particularly strong for propositions of free international trade and capital flows. In contrast, macroeconomic propositions exhibit a lower degree of consensus, partly because of increased agreement with monetarist and supply-side propositions over time. The profession displays substantial skepticism concerning claims of the "New Economy.".

  DOI：

  10.1080/00220480309595230

文献信息

• Consensus Among Economists: Revisited
  作者：Dan Fuller、Doris Geide-stevenson

  DOI：10.1080/00220480309595230

  日期：2003.1

  The authors explore consensus among economists on specific propositions on the basis of a fall 2000 survey of American Economic Association members. Because some propositions are drawn from earlier studies, the results illustrate the dynamics of opinion within the profession. The authors generally find consensus within the profession, although the degree of consensus varies between propositions that are international, macroeconomic, and microeconomic in nature. Consensus is particularly strong for propositions of free international trade and capital flows. In contrast, macroeconomic propositions exhibit a lower degree of consensus, partly because of increased agreement with monetarist and supply-side propositions over time. The profession displays substantial skepticism concerning claims of the "New Economy.".
• Facile Deprotection of Trimethylsilyl Ethers With Modified Borohydride Agents; 1-Benzyl-4-AZA-1-Azoniabicyclo[2.2.2]Octane Tetrahydroborate (Baaotb)¹Versus Tetrabutylammonium Tetrahydroborate(TBATB)
  作者：H. Firouzabadi、G. R. Afsharifar

  DOI：10.1080/00397919608003713

  日期：1996.3

  Deprotection of structurally different trimethylsilyl ethers with the modified borohydride agents BAAOTB and TBATB to their corresponding alcohols in reflexing t-BuOH is described. Both BAAOTB and TBATB are efficient reagents for this purpose. BAAOTB seems to be more selective than TBATB.