1,3-bis(3-ammoniumpropyl)tetramethyldisiloxane carbamate | 1498252-03-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,3-bis(3-ammoniumpropyl)tetramethyldisiloxane carbamate
• CAS: 1498252-03-1
• 化学式: C₁₁H₂₈N₂O₃Si₂
• 分子量: 292.526
• InChiKey: DGVOMNUKPKFQDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.42
• 重原子数：
  18.0
• 可旋转键数：
  9.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  84.58
• 氢给体数：
  3.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  1,3-双(3-氨基丙基)-1,1,3,3-四甲基二硅氧烷 、 二氧化碳 、 4-咪唑甲醛 以 甲醇 为溶剂， 反应 4.0h， 生成 1,3-bis(3-ammoniumpropyl)tetramethyldisiloxane carbamate
  参考文献：
  名称：

  A new zwitterionic siloxane compound: structural characterization, the solution behavior and surface properties evaluation

  摘要：

  1,3-Bis(3-ammonium-propyl)tetramethyldisiloxane carbamate, APCO, was unexpected formed in a solution containing the proper diamine besides 4-imidazolecarboxaldehyde in methanol solution maintained for long time at room temperature. The compound separated as colourless crystalline one was investigated by singlecrystal X-ray diffraction and spectral (FT-IR, H-1-NMR) analysis. Due to the co-existence of both hydrophobic bis(propyl)tetramethyldisiloxane fragment and telechelic hydrophilic groups, the obtained compound shows surface activity proved by tensiometry. Self-assembly in solution was emphasized by dynamic light scattering (DLS) and confirmed by atomic force microscopy (AFM) images taken on the spin coated films, both revealing closed values for size of the micelles (few hundred nanometers). The behavior of the carbamate in wet atmosphere was studied by water vapor sorption analysis in dynamic regime (DVS). Thermal analysis revealed almost a complete decomposition of the compound occurring in a two-steps process. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molliq.2014.04.004