diethyl-diiodo-λ⁴-tellane | 41235-19-2

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: diethyl-diiodo-λ⁴-tellane
• 英文别名: diethyltellane diiodide；diethyl tellurium diiodide；Diaethyltellurdijodid；Diethyltelluriumdiiodid；Diaethyl-tellurdijodid；Diethyl-diiod-tellur；[Ethyl(diiodo)-lambda4-tellanyl]ethane；[ethyl(diiodo)-λ4-tellanyl]ethane
• CAS: 41235-19-2
• 化学式: C₄H₁₀I₂Te
• 分子量: 439.532
• InChiKey: UEXOASMGEBRJIB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.34
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  diethyl-diiodo-λ⁴-tellane 、 氯磺酸 以40%的产率得到
  参考文献：
  名称：

  SIDDIQI, Z. A.;SHAKIR, M.;ASLAM, M.;ZAIDI, S. A. A., SYNTH. AND REACT. INORG. AND METAL-ORG. CHEM., 1983, 13, N 2, 173-181

  摘要：

  DOI：
• 作为产物：
  描述：

  碘乙烷 、 碲化氢 以 not given 为溶剂， 生成 diethyl-diiodo-λ⁴-tellane
  参考文献：
  名称：

  Scott, A., Proceedings of the Chemical Society, London, 1904, vol. 20, p. 156 - 156

  摘要：

  DOI：

文献信息

• Synthesis, spectroscopic characterization, and in vitro antimicrobial study of novel organotellurium (IV) diphenyldithiocarbamate derivatives
  作者：Chandan Maurya、Sangeeta Bajpai、Pramod Kumar Kushwaha、Umesh Chand、Sunita Singh

  DOI：10.1080/17415993.2024.2360441

  日期：2024.7.3

  Three novel organotellurium (IV) derivatives of diphenyldithiocarbamate, C4H8Te[(CS2) N(C6H5)2]2 (1), (C2H5)2Te[(CS2) N(C6H5)2]2 (2), and C4H7(CH3)Te[(CS2) N(C6H5)2]2 (3) have been synthesized by t...

  二苯基二硫代氨基甲酸酯的三种新型有机碲 (IV) 衍生物：C4H8Te[(CS2) N(C6H5)2]2 (1)、(C2H5)2Te[(CS2) N( )2]2 (2) 和 C4H7(CH3) Te[(CS2) N( )2]2 (3) 已通过...合成
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Te: MVol., 66, page 236 - 238
  作者：

  DOI：——

  日期：——
• Gilbert; Lowry, Journal of the Chemical Society, 1928, p. 3183
  作者：Gilbert、Lowry

  DOI：——

  日期：——
• Organotellurium(IV) derivatives: Synthesis and characterization of metal dialkyltetrakis(chlorosulphato)tellurate(IV), M2[R2Te(SO3Cl)4] (M  Na, K) and Sn[R2Te(SO3Cl)4] (R  CH3, C2H5, n-C3H7, n-C4H9
  作者：M Shakir、P.Shahul Hameed、Farha Firdaus、Saji P Varkey

  DOI：10.1016/0277-5387(94)00392-r

  日期：1995.5

  The ability of R(2)Te(SO3Cl)(2) (R = CH3, C2H5, n-C3H7, n-C4H9) compounds to behave as a SO3Cl- accepters has been proved by the synthesis and characterization of new monomeric complexes of the type M(2)[R(2)Te(SO3Cl)(4)] (M = Na, K) and Sn[R(2)Te (SO3Cl)(4)] by reacting stoichiometric amounts of R(2)TeI(2) (R = CH3, C2H5, n-C3H7, n-C4H9) with metal salts, namely NaI, KI and SnCl2, in excess HSO3Cl. The compounds are hygroscopic in nature but are stable under dry nitrogen. The IR spectra of the compounds suggest that the SO3Cl- is covalently bonded to the dialkyltellurium moiety. The observed molar conductance values of these compounds in DMSO confirm that they are 1:1 and 1:2 electrolytes. The H-1 NMR spectra are discussed in terms of inductive effects and since the chlorosulphate group is expected to be bound in monodentate manner the hexacoordination around the tellurium atom is maintained.
• Vernon, Journal of the Chemical Society, 1921, vol. 119, p. 695 Anm.
  作者：Vernon

  DOI：——

  日期：——