(diethyl ether)pentachlorotungsten | 19428-46-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: (diethyl ether)pentachlorotungsten
• CAS: 19428-46-7
• 化学式: C₄H₁₀Cl₅OW
• 分子量: 435.238
• InChiKey: YDPFUVXBKWTVLM-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (diethyl ether)pentachlorotungsten 在 四氢呋喃 作用下， 以 四氢呋喃 为溶剂， 生成 trichloro-oxobis(tetrahydrofuran)tungsten(V)
  参考文献：
  名称：

  Reduction of WCl6 by allyltrimethylsilane. A convenient method to prepare WCl5(OEt2) and some other derivatives of WCl5

  摘要：

  WCl6 was reacted with excess allyltrimethylsilane in diethyl ether solution at low temperature. The main product in the reaction was shown to be WCl5(OEt2) which was isolated as black-green air- and moisture-sensitive crystals. WCl5(OEt2) was reacted with different Lewis bases, e.g. pyridine and 9-fluorenone to yield the new compounds WCl5 (pyridine) and WCl5(9-fluorenone). The latter most likely being an oxygen bonded complex.

  DOI：

  10.1016/s0277-5387(00)86127-6
• 作为产物：
  描述：

  乙醚 、 六氯化钨 在 烯丙基三甲基硅烷 作用下， 以 乙醚 为溶剂， 以64%的产率得到(diethyl ether)pentachlorotungsten
  参考文献：
  名称：

  Reduction of WCl6 by allyltrimethylsilane. A convenient method to prepare WCl5(OEt2) and some other derivatives of WCl5

  摘要：

  WCl6 was reacted with excess allyltrimethylsilane in diethyl ether solution at low temperature. The main product in the reaction was shown to be WCl5(OEt2) which was isolated as black-green air- and moisture-sensitive crystals. WCl5(OEt2) was reacted with different Lewis bases, e.g. pyridine and 9-fluorenone to yield the new compounds WCl5 (pyridine) and WCl5(9-fluorenone). The latter most likely being an oxygen bonded complex.

  DOI：

  10.1016/s0277-5387(00)86127-6

文献信息

• tBuOSiMe3, a facile oxygen-transfer reagent. Preparation of WOCl4, WOCl3dme, MoOCl3dme, [WOCl2dme]2O and [MoOCl2dme]2O by oxygen-transfer reactions (dme = 1,2-dimethoxyethane)
  作者：Christina Persson、Carlaxel Andersson

  DOI：10.1016/s0277-5387(00)86021-0

  日期：1992.1

  Monomeric and mu-oxo bridged dimeric oxohalide complexes of tungsten(V) and molybdenum(V) are conveniently prepared using tbutyl-trimethylsilyl ether as an oxygen-transfer reagent.