bis(N,N-diethyldiselenocarbamato)palladium(II) | 19400-60-3

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: bis(N,N-diethyldiselenocarbamato)palladium(II)
• CAS: 19400-60-3
• 化学式: C₁₀H₂₀N₂PdSe₄
• 分子量: 590.542
• InChiKey: FFOLZIRRTONEEZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  17.0
• 可旋转键数：
  6.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  bis(N,N-diethyldiselenocarbamato)palladium(II) 、 bis-triphenylphosphine-palladium(II) chloride 以 苯 为溶剂， 以60%的产率得到chloro(N,N-diethyldiselenocarbamato)(triphenylphosphine)palladium(II)
  参考文献：
  名称：

  Pan, Wie-Hin; Fackler Jr., John P.; Chen, Inorganic Chemistry, 1981, vol. 20, # 3, p. 856 - 863

  摘要：

  DOI：

文献信息

• Ligand exchange reactions between metal(II) chelates of different sulfur and selenium containing ligands X. Exchange behavior of chelates of 1,3-dithiole-2-thione-4,5-diselenolate (dsit) and 1,1-dichalcogenolates. X-ray structure of Bu4N[Pd(dsit) (Et2dsc)]
  作者：Ruth-Maria Olk、Wolfgang Dietzsch、Jörg Kahlmeier、Peter Jörchel、Reinhard Kirmse、Joachim Sieler

  DOI：10.1016/s0020-1693(96)05163-8

  日期：1997.1

  Copper, nickel and palladium bis-chelates of 1,3-dithiole-2-thione-4,5-diselenolate (dsit) react with geminal dichalcogenolates (L) of these metals in acetone (M = Pd: acetonitrile) forming the mixed-ligand complexes [M(dsit)L](n-) exclusively when n = 1 and L = Et(2)NCXY(-): X = Y = S (Et(2)dtc), X = S, Y = Se (Et(2)tsc), X = Y = Se (Et(2)dsc) or n = 2 and L = (CN)(2)C double bond CXY(2-): X = Y = S (i-mnt), X = S, Y = Se (i-mnts), X = S = Se (i-mns), which can be isolated as salts of suitable cations. EPR measurements on the copper, UV-Vis spectroscopy on the nickel, and C-13/Se-77 NMR measurements on the palladium complexes are used for characterizing the complexes. The mixed-ligand compound Bu(4)N[Pd(dsit)(Et(2)dsc)] crystallized orthorhombic, space group Fdd2 with 16 molecules in the unit cell; a = 36,585(4), b = 29,219(3), c = 12,0708(2) Angstrom.